Abstract
A novel N,N’-allyl-bridged bisimidazolium salt and a novel dinuclear Ag(I) and a Au(I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl-group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd(II).
Original language | English |
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Pages (from-to) | 1848-1851 |
Number of pages | 4 |
Journal | Chemistry - An Asian Journal |
Volume | 15 |
Issue number | 12 |
DOIs | |
State | Published - 17 Jun 2020 |
Keywords
- Gold
- Isomerisation
- N-Heterocyclic Carbenes
- Photochemistry
- Silver