Dinuclear Gold(I) Complexes Bearing N,N′-Allyl-Bridged Bisimidazolylidene Ligands

Christian H.G. Jakob, Bruno Dominelli, Julia Rieb, Christian Jandl, Alexander Pöthig, Robert M. Reich, João D.G. Correia, Fritz E. Kühn

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

A novel N,N’-allyl-bridged bisimidazolium salt and a novel dinuclear Ag(I) and a Au(I) NHC complex are reported. Both metallacyclic complexes have a twisted structural shape due to the rigid allylic system and form two different isomers relating to the position of the double bonds. The allyl-group shows photoisomerisation, but no reactivity towards bases for the additional coordination of Pd(II).

Original languageEnglish
Pages (from-to)1848-1851
Number of pages4
JournalChemistry - An Asian Journal
Volume15
Issue number12
DOIs
StatePublished - 17 Jun 2020

Keywords

  • Gold
  • Isomerisation
  • N-Heterocyclic Carbenes
  • Photochemistry
  • Silver

Fingerprint

Dive into the research topics of 'Dinuclear Gold(I) Complexes Bearing N,N′-Allyl-Bridged Bisimidazolylidene Ligands'. Together they form a unique fingerprint.

Cite this