Diels‐Alder Reaction of Cyclopentadiene with Acrylic Acid Derivatives in Heterogeneous Phases

Harun Parlar, Rotraud Baumann

Research output: Contribution to journalArticlepeer-review

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Abstract

The ratio of exo‐/endo‐adducts formed in the reaction of acrylic acid derivatives 1 with cyclopentadiene is hardly influenceable in the homogeneous phase; in contrast, in the heterogeneous phase it strongly depends on the carrier material. For example, when acrylonitrile reacts with cyclopentadiene in a homogeneous phase to give the products in the ratio 3:1, the same reaction on Al2O3 leads to a ratio of almost 1:1. (Figure Presented.)

Original languageEnglish
Pages (from-to)1014
Number of pages1
JournalAngewandte Chemie International Edition in English
Volume20
Issue number12
DOIs
StatePublished - Dec 1981
Externally publishedYes

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