Dications Based on a Hydrotris(phosphonio)borate Skeleton

Hubert Schmidbaur; Thomas Wimmer; Gabriele Reber; Gerhard Müller

doi:10.1002/anie.198810711

Dications Based on a Hydrotris(phosphonio)borate Skeleton

Hubert Schmidbaur
, Thomas Wimmer
, Gabriele Reber
, Gerhard Müller

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

The first two dications having a [HBP₃]^{2 ⊕} framework (1 and 2)—the boron atom is surrounded by three phosphonium centers and a hydrogen atom—were isolated as dibromides and characterized by X‐ray structure analysis. The stability of the two salts toward air and moisture is remarkable. The boron‐bonded H atom is exchanged for a D atom in alkaline D₂O. (Figure Presented.)

Original language	English
Pages (from-to)	1071-1074
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	27
Issue number	8
DOIs	https://doi.org/10.1002/anie.198810711
State	Published - Aug 1988

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title = "Dications Based on a Hydrotris(phosphonio)borate Skeleton",

abstract = "The first two dications having a [HBP3]2 ⊕ framework (1 and 2)—the boron atom is surrounded by three phosphonium centers and a hydrogen atom—were isolated as dibromides and characterized by X‐ray structure analysis. The stability of the two salts toward air and moisture is remarkable. The boron‐bonded H atom is exchanged for a D atom in alkaline D2O. (Figure Presented.)",

author = "Hubert Schmidbaur and Thomas Wimmer and Gabriele Reber and Gerhard M{\"u}ller",

year = "1988",

month = aug,

doi = "10.1002/anie.198810711",

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AU - Schmidbaur, Hubert

AU - Wimmer, Thomas

AU - Reber, Gabriele

AU - Müller, Gerhard

PY - 1988/8

Y1 - 1988/8

N2 - The first two dications having a [HBP3]2 ⊕ framework (1 and 2)—the boron atom is surrounded by three phosphonium centers and a hydrogen atom—were isolated as dibromides and characterized by X‐ray structure analysis. The stability of the two salts toward air and moisture is remarkable. The boron‐bonded H atom is exchanged for a D atom in alkaline D2O. (Figure Presented.)

AB - The first two dications having a [HBP3]2 ⊕ framework (1 and 2)—the boron atom is surrounded by three phosphonium centers and a hydrogen atom—were isolated as dibromides and characterized by X‐ray structure analysis. The stability of the two salts toward air and moisture is remarkable. The boron‐bonded H atom is exchanged for a D atom in alkaline D2O. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84990158051

U2 - 10.1002/anie.198810711

DO - 10.1002/anie.198810711

M3 - Article

AN - SCOPUS:84990158051

SN - 0570-0833

VL - 27

SP - 1071

EP - 1074

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 8

ER -

Dications Based on a Hydrotris(phosphonio)borate Skeleton

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