Diastereoselective hydrogenation of arenes and pyridines using supported ruthenium nanoparticles under mild conditions

Florian Bourriquen, Julien Hervochon, Ruiyang Qu, Stephan Bartling, Nils Rockstroh, Kathrin Junge, Cédric Fischmeister, Matthias Beller

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

A convenient and practical diastereoselective cis-hydrogenation of multi-substituted pyridines and arenes is reported. Applying a novel heterogeneous ruthenium catalyst, the corresponding piperidines and cyclohexanes are obtained in high yields (typically >80%) with a good functional group tolerance under mild conditions. The robust ruthenium supported catalyst is smoothly prepared and can be reused multiple times without activity loss.

Original languageEnglish
Pages (from-to)8842-8845
Number of pages4
JournalChemical Communications
Volume58
Issue number63
DOIs
StatePublished - 18 Jul 2022
Externally publishedYes

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