TY - JOUR
T1 - Development and Application of Highly Efficient Ruthenium-Based Catalysts for the Ring Opening Metathesis Polymerization
AU - Glander, S. C.
AU - Nuyken, O.
AU - Schattenmann, W. C.
AU - Herrmann, W. A.
PY - 1998/2
Y1 - 1998/2
N2 - Various bisallylic ruthenium(IV) complexes were synthesized and tested as catalysts for the ring opening metathesis polymerization (ROMP) of norbornene. In presence of cocatalysts such as silanes or certain diazoalkanes a significant increase of the catalytic activity could be observed. With these highly efficient systems the ROMP of diolefinic norbornene derivatives (dicyclopentadiene, 5-ethylidene-2-norbornene, norbornadiene) and monomers containing functional groups was achieved (e.g. alcohols, acids, esters, amides, imides, ketones, aldehydes, ...).
AB - Various bisallylic ruthenium(IV) complexes were synthesized and tested as catalysts for the ring opening metathesis polymerization (ROMP) of norbornene. In presence of cocatalysts such as silanes or certain diazoalkanes a significant increase of the catalytic activity could be observed. With these highly efficient systems the ROMP of diolefinic norbornene derivatives (dicyclopentadiene, 5-ethylidene-2-norbornene, norbornadiene) and monomers containing functional groups was achieved (e.g. alcohols, acids, esters, amides, imides, ketones, aldehydes, ...).
UR - http://www.scopus.com/inward/record.url?scp=0032340718&partnerID=8YFLogxK
U2 - 10.1002/masy.19981270112
DO - 10.1002/masy.19981270112
M3 - Article
AN - SCOPUS:0032340718
SN - 1022-1360
VL - 127
SP - 67
EP - 75
JO - Macromolecular Symposia
JF - Macromolecular Symposia
ER -