Detailed product energy distributions for exothermic triatomic exchange reactions from a statistical dynamic model

G. Venzl; S. F. Fischer

doi:10.1016/0301-0104(78)87136-5

Detailed product energy distributions for exothermic triatomic exchange reactions from a statistical dynamic model

G. Venzl, S. F. Fischer

TUM Emeriti of Excellence

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A statistical dynamic model which has been proposed in an earlier publication is refined in order to discuss rotational distributions and applied to some representative examples. It relies on a Franck-Condon type description of the collinear rearrangement. Rotational states are assumed to be "a priori" equally probable. Detailed vibration-rotational distributions for H(D) + F², H(D) + Cl², and Cl + H(D)I reactions show good agreement with experimental findings.

Original language	English
Pages (from-to)	305-312
Number of pages	8
Journal	Chemical Physics
Volume	33
Issue number	2
DOIs	https://doi.org/10.1016/0301-0104(78)87136-5
State	Published - 15 Sep 1978

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title = "Detailed product energy distributions for exothermic triatomic exchange reactions from a statistical dynamic model",

abstract = "A statistical dynamic model which has been proposed in an earlier publication is refined in order to discuss rotational distributions and applied to some representative examples. It relies on a Franck-Condon type description of the collinear rearrangement. Rotational states are assumed to be {"}a priori{"} equally probable. Detailed vibration-rotational distributions for H(D) + F2, H(D) + Cl2, and Cl + H(D)I reactions show good agreement with experimental findings.",

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N2 - A statistical dynamic model which has been proposed in an earlier publication is refined in order to discuss rotational distributions and applied to some representative examples. It relies on a Franck-Condon type description of the collinear rearrangement. Rotational states are assumed to be "a priori" equally probable. Detailed vibration-rotational distributions for H(D) + F2, H(D) + Cl2, and Cl + H(D)I reactions show good agreement with experimental findings.

AB - A statistical dynamic model which has been proposed in an earlier publication is refined in order to discuss rotational distributions and applied to some representative examples. It relies on a Franck-Condon type description of the collinear rearrangement. Rotational states are assumed to be "a priori" equally probable. Detailed vibration-rotational distributions for H(D) + F2, H(D) + Cl2, and Cl + H(D)I reactions show good agreement with experimental findings.

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Detailed product energy distributions for exothermic triatomic exchange reactions from a statistical dynamic model

Abstract

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