C₂-Symmetric ansa-lanthanidocene complexes. Synthesis via silylamine elimination and β-SiH agostic rigidity

Keyphrases

• Agostic 100%
• Ansa 100%
• C2-symmetric 100%
• Indene 100%
• Silylamine 100%
• Elimination Reactions 66%
• Metallocene Complexes 66%
• X-ray Crystallography 33%
• Metal Center 33%
• Molecular Structure 33%
• Chelates 33%
• 1H-13C 33%
• N-Si 33%
• Spectroscopic Characterization 33%
• Structural Features 33%
• Metallacycles 33%
• X-ray Structural Analysis 33%
• Racemic 33%
• Electron-deficient 33%
• Coupling Constant 33%
• Structural Characterization 33%
• Si-N 33%
• Ligand Exchange 33%
• Indenyl 33%
• Multinuclear NMR 33%
• Bite Angle 33%
• Reaction Intermediates 33%
• 29Si 33%
• Mechanistic Details 33%
• Stretching Vibration 33%
• Heteroleptic 33%
• Lanthanide Ions 33%
• Ancillary Ligand 33%
• Fluorene 33%
• Irm-NMR 33%
• Amide Ligand 33%
• Silylamide 33%
• Substituted Cyclopentadienes 33%
• Ate Complex 33%
• PKa Values 33%

Chemistry

• Indene 100%
• Metallocene 66%
• Elimination Reaction 66%
• Cyclopentadiene 33%
• Metallacycle 33%
• Lanthanoid Atom 33%
• Carboxamide 33%
• Dissociation Exponent 33%
• Stretching Vibration 33%
• Fluorene 33%
• 13C{1H}-NMR Spectroscopy 33%
• Molecular Structure 33%
• Reaction Intermediate 33%
• X-Ray Crystallography 33%