TY - JOUR
T1 - Crystal structure of bis(trimethylphosphine)iminium bromide monohydrate, [Me3P=N=PMe3]Br·H2O
AU - Rankin, David W.H.
AU - Walkinshaw, Malcolm D.
AU - Schmidbaur, Hubert
PY - 1982
Y1 - 1982
N2 - The crystal structure of the title compound has been determined by X-ray analysis. The crystals are triclinic, space group P1, with a = 9.685(1), b = 11.449(4), c = 18.173(2) Å, α = 90.55(2), β = 91.50(1), and γ = 108.93(2)°, and Z = 6. The structure refined to R = 0.059 using 4 103 independent reflections. There are three crystallographically independent [Me3P=N=PMe3]+ cations, with mean PNP angles of 137.0°and mean P=N distances of 1.582 Å. The anions and water of crystallisation are present in hydrogen-bonded Br6(H2O)66- units.
AB - The crystal structure of the title compound has been determined by X-ray analysis. The crystals are triclinic, space group P1, with a = 9.685(1), b = 11.449(4), c = 18.173(2) Å, α = 90.55(2), β = 91.50(1), and γ = 108.93(2)°, and Z = 6. The structure refined to R = 0.059 using 4 103 independent reflections. There are three crystallographically independent [Me3P=N=PMe3]+ cations, with mean PNP angles of 137.0°and mean P=N distances of 1.582 Å. The anions and water of crystallisation are present in hydrogen-bonded Br6(H2O)66- units.
UR - http://www.scopus.com/inward/record.url?scp=37049105440&partnerID=8YFLogxK
U2 - 10.1039/DT9820002317
DO - 10.1039/DT9820002317
M3 - Article
AN - SCOPUS:37049105440
SN - 1472-7773
SP - 2317
EP - 2320
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 12
ER -