Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide

Gerald L. Wegner; Alexander Jockisch; Annette Schier; Hubert Schmidbaur

doi:10.1515/znb-2000-0501

Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide

Gerald L. Wegner, Alexander Jockisch, Annette Schier, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Treatment of bis[bis(trimethylsilyl)amino]germanium(II) with elemental sulfur or selenium affords high yields of the corresponding monosulfide [(Me₃Si)₂N]₂GeS and selenide [(Me₃Si)₂N]₂GeSe, respectively. The crystalline products have now been shown to be cyclic dimers with (GeS/Se)₂ four-membered rings by X-ray single crystal structure analysis. The crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide (Ph₃P)Au-N(SiMe₃)₂ has also been determined. The molecule is a monomer with a tricoordinate nitrogen atom in a planar configuration [Si₂NAu]. The compound does not undergo insertion of the bis[bis(trimethylsilyl)amino]germylene.

Original language	English
Pages (from-to)	347-351
Number of pages	5
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	55
Issue number	5
DOIs	https://doi.org/10.1515/znb-2000-0501
State	Published - May 2000

Keywords

Germanium(II) Amides
Germylenes
Sulfurization

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Wegner, G. L., Jockisch, A., Schier, A., & Schmidbaur, H. (2000). Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 55(5), 347-351. https://doi.org/10.1515/znb-2000-0501

Wegner, Gerald L. ; Jockisch, Alexander ; Schier, Annette et al. / Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide. In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2000 ; Vol. 55, No. 5. pp. 347-351.

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title = "Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide",

abstract = "Treatment of bis[bis(trimethylsilyl)amino]germanium(II) with elemental sulfur or selenium affords high yields of the corresponding monosulfide [(Me3Si)2N]2GeS and selenide [(Me3Si)2N]2GeSe, respectively. The crystalline products have now been shown to be cyclic dimers with (GeS/Se)2 four-membered rings by X-ray single crystal structure analysis. The crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide (Ph3P)Au-N(SiMe3)2 has also been determined. The molecule is a monomer with a tricoordinate nitrogen atom in a planar configuration [Si2NAu]. The compound does not undergo insertion of the bis[bis(trimethylsilyl)amino]germylene.",

keywords = "Germanium(II) Amides, Germylenes, Sulfurization",

author = "Wegner, {Gerald L.} and Alexander Jockisch and Annette Schier and Hubert Schmidbaur",

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Wegner, GL, Jockisch, A, Schier, A & Schmidbaur, H 2000, 'Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide', Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, vol. 55, no. 5, pp. 347-351. https://doi.org/10.1515/znb-2000-0501

Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide. / Wegner, Gerald L.; Jockisch, Alexander; Schier, Annette et al.
In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 55, No. 5, 05.2000, p. 347-351.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide

AU - Wegner, Gerald L.

AU - Jockisch, Alexander

AU - Schier, Annette

AU - Schmidbaur, Hubert

PY - 2000/5

Y1 - 2000/5

N2 - Treatment of bis[bis(trimethylsilyl)amino]germanium(II) with elemental sulfur or selenium affords high yields of the corresponding monosulfide [(Me3Si)2N]2GeS and selenide [(Me3Si)2N]2GeSe, respectively. The crystalline products have now been shown to be cyclic dimers with (GeS/Se)2 four-membered rings by X-ray single crystal structure analysis. The crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide (Ph3P)Au-N(SiMe3)2 has also been determined. The molecule is a monomer with a tricoordinate nitrogen atom in a planar configuration [Si2NAu]. The compound does not undergo insertion of the bis[bis(trimethylsilyl)amino]germylene.

AB - Treatment of bis[bis(trimethylsilyl)amino]germanium(II) with elemental sulfur or selenium affords high yields of the corresponding monosulfide [(Me3Si)2N]2GeS and selenide [(Me3Si)2N]2GeSe, respectively. The crystalline products have now been shown to be cyclic dimers with (GeS/Se)2 four-membered rings by X-ray single crystal structure analysis. The crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide (Ph3P)Au-N(SiMe3)2 has also been determined. The molecule is a monomer with a tricoordinate nitrogen atom in a planar configuration [Si2NAu]. The compound does not undergo insertion of the bis[bis(trimethylsilyl)amino]germylene.

KW - Germanium(II) Amides

KW - Germylenes

KW - Sulfurization

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Wegner GL, Jockisch A, Schier A, Schmidbaur H. Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide. Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. 2000 May;55(5):347-351. doi: 10.1515/znb-2000-0501

Crystal and molecular structures of the sulfurization and selenation products of bis[bis(trimethylsilyl)amino]germanium(II). Crystal structure of (triphenylphosphine)gold(I) bis(trimethylsilyl)amide

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