Correlation of Adsorption Structure and Reactivity in Zeolite Catalyzed Amination

A. Kogelbauer; Ch Gründling; J. A. Lercher

doi:10.1016/S0167-2991(08)63690-3

Correlation of Adsorption Structure and Reactivity in Zeolite Catalyzed Amination

A. Kogelbauer
, Ch Gründling
, J. A. Lercher

University of Pittsburgh
University of Twente

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The surface chemistry of ammonia and methanol on alkali exchnged and Brønsted acidic mordenites and erionites is correlated with the kinetic analysis of shape selective methylamine synthesis. The results suggest that over alkali exchanged molecular sieves the reaction proceeds via methanolysis of chemisorbed methanol and over the Brønsted acidic form via methanolysis of chemisorbed ammonia.

Original language	English
Pages (from-to)	1475-1482
Number of pages	8
Journal	Studies in Surface Science and Catalysis
Volume	84
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(08)63690-3
State	Published - 1 Jan 1994
Externally published	Yes

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@article{cf976962f92e45db9df68fb6c3482b56,

title = "Correlation of Adsorption Structure and Reactivity in Zeolite Catalyzed Amination",

abstract = "The surface chemistry of ammonia and methanol on alkali exchnged and Br{\o}nsted acidic mordenites and erionites is correlated with the kinetic analysis of shape selective methylamine synthesis. The results suggest that over alkali exchanged molecular sieves the reaction proceeds via methanolysis of chemisorbed methanol and over the Br{\o}nsted acidic form via methanolysis of chemisorbed ammonia.",

author = "A. Kogelbauer and Ch Gr{\"u}ndling and Lercher, \{J. A.\}",

note = "Funding Information: This work was supported by the Christian Doppler Laboratory for Heterogeneous Catalysis and the {"}Fonds zur Forderung der Wissenschafllichen Forschung{"} under project P73 12 CHE. We are gratehl for receiving the mordenite samples from the Japanese Catalysis Society.",

year = "1994",

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day = "1",

doi = "10.1016/S0167-2991(08)63690-3",

language = "English",

volume = "84",

pages = "1475--1482",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier Inc.",

number = "C",

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TY - JOUR

T1 - Correlation of Adsorption Structure and Reactivity in Zeolite Catalyzed Amination

AU - Kogelbauer, A.

AU - Gründling, Ch

AU - Lercher, J. A.

N1 - Funding Information: This work was supported by the Christian Doppler Laboratory for Heterogeneous Catalysis and the "Fonds zur Forderung der Wissenschafllichen Forschung" under project P73 12 CHE. We are gratehl for receiving the mordenite samples from the Japanese Catalysis Society.

PY - 1994/1/1

Y1 - 1994/1/1

N2 - The surface chemistry of ammonia and methanol on alkali exchnged and Brønsted acidic mordenites and erionites is correlated with the kinetic analysis of shape selective methylamine synthesis. The results suggest that over alkali exchanged molecular sieves the reaction proceeds via methanolysis of chemisorbed methanol and over the Brønsted acidic form via methanolysis of chemisorbed ammonia.

AB - The surface chemistry of ammonia and methanol on alkali exchnged and Brønsted acidic mordenites and erionites is correlated with the kinetic analysis of shape selective methylamine synthesis. The results suggest that over alkali exchanged molecular sieves the reaction proceeds via methanolysis of chemisorbed methanol and over the Brønsted acidic form via methanolysis of chemisorbed ammonia.

UR - https://www.scopus.com/pages/publications/0001658727

U2 - 10.1016/S0167-2991(08)63690-3

DO - 10.1016/S0167-2991(08)63690-3

M3 - Article

AN - SCOPUS:0001658727

SN - 0167-2991

VL - 84

SP - 1475

EP - 1482

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

IS - C

ER -

Correlation of Adsorption Structure and Reactivity in Zeolite Catalyzed Amination

Abstract

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