Convenient large scale in situ synthesis of 3-(N,N-dialkylamino)-1,1- bis(trimethylsilyl)-propyllithium: Source of a new sterically demanding γ-donor functionalized alkyl ligand

Markus M. Schulte; Roland A. Fischer

doi:10.1039/C39940002609

Convenient large scale in situ synthesis of 3-(N,N-dialkylamino)-1,1- bis(trimethylsilyl)-propyllithium: Source of a new sterically demanding γ-donor functionalized alkyl ligand

Markus M. Schulte, Roland A. Fischer

Chair of Inorganic and Organometallic Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The addition of Li[CH₂NR₂] to the olefin [Me ₃Si]₂C=CH₂ yields almost quantitatively the new γ-donor functionalized organolithium compounds (Me₃Si) ₂C(Li)CH₂CH₂NR₂ which are used to synthesize the intramolecularly adduct stabilized organo-gallium and -zinc complexes R₂GaC(SiMe₃)₂CH₂CH ₂NR₂, {ClZnC(SiMe₃)₂CH ₂CH₂NR₂NR₂}₂.

Original language	English
Pages (from-to)	2609-2610
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C39940002609
State	Published - 1994

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title = "Convenient large scale in situ synthesis of 3-(N,N-dialkylamino)-1,1- bis(trimethylsilyl)-propyllithium: Source of a new sterically demanding γ-donor functionalized alkyl ligand",

abstract = "The addition of Li[CH2NR2] to the olefin [Me 3Si]2C=CH2 yields almost quantitatively the new γ-donor functionalized organolithium compounds (Me3Si) 2C(Li)CH2CH2NR2 which are used to synthesize the intramolecularly adduct stabilized organo-gallium and -zinc complexes R2GaC(SiMe3)2CH2CH 2NR2, {ClZnC(SiMe3)2CH 2CH2NR2NR2}2.",

author = "Schulte, {Markus M.} and Fischer, {Roland A.}",

year = "1994",

doi = "10.1039/C39940002609",

language = "English",

pages = "2609--2610",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "22",

}

Convenient large scale in situ synthesis of 3-(N,N-dialkylamino)-1,1- bis(trimethylsilyl)-propyllithium: Source of a new sterically demanding γ-donor functionalized alkyl ligand. / Schulte, Markus M.; Fischer, Roland A.
In: Journal of the Chemical Society, Chemical Communications, No. 22, 1994, p. 2609-2610.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Convenient large scale in situ synthesis of 3-(N,N-dialkylamino)-1,1- bis(trimethylsilyl)-propyllithium

T2 - Source of a new sterically demanding γ-donor functionalized alkyl ligand

AU - Schulte, Markus M.

AU - Fischer, Roland A.

PY - 1994

Y1 - 1994

N2 - The addition of Li[CH2NR2] to the olefin [Me 3Si]2C=CH2 yields almost quantitatively the new γ-donor functionalized organolithium compounds (Me3Si) 2C(Li)CH2CH2NR2 which are used to synthesize the intramolecularly adduct stabilized organo-gallium and -zinc complexes R2GaC(SiMe3)2CH2CH 2NR2, {ClZnC(SiMe3)2CH 2CH2NR2NR2}2.

AB - The addition of Li[CH2NR2] to the olefin [Me 3Si]2C=CH2 yields almost quantitatively the new γ-donor functionalized organolithium compounds (Me3Si) 2C(Li)CH2CH2NR2 which are used to synthesize the intramolecularly adduct stabilized organo-gallium and -zinc complexes R2GaC(SiMe3)2CH2CH 2NR2, {ClZnC(SiMe3)2CH 2CH2NR2NR2}2.

UR - http://www.scopus.com/inward/record.url?scp=0344381557&partnerID=8YFLogxK

U2 - 10.1039/C39940002609

DO - 10.1039/C39940002609

M3 - Article

AN - SCOPUS:0344381557

SN - 0022-4936

SP - 2609

EP - 2610

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 22

ER -

Convenient large scale in situ synthesis of 3-(N,N-dialkylamino)-1,1- bis(trimethylsilyl)-propyllithium: Source of a new sterically demanding γ-donor functionalized alkyl ligand

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