Continuous hydroamination in a liquid-liquid two-phase system

Volker Neff; Thomas E. Müller; Johannes A. Lercher

doi:10.1039/b111630d

Continuous hydroamination in a liquid-liquid two-phase system

Volker Neff
, Thomas E. Müller
, Johannes A. Lercher

Chair of Chemical Technology II

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

58 Scopus citations

Abstract

The direct addition of NH across a CC multiple bond (hydroamination) was efficiently catalysed in a liquid-liquid two-phase system. The latter comprised a polar catalyst phase of Zn(CF₃SO₃)₂ in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate and a substrate mixture in heptane. The possibility of catalysing different hydroamination reactions continuously was demonstrated.

Original language	English
Pages (from-to)	906-907
Number of pages	2
Journal	Chemical Communications
Volume	2
Issue number	8
DOIs	https://doi.org/10.1039/b111630d
State	Published - 2002

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abstract = "The direct addition of NH across a CC multiple bond (hydroamination) was efficiently catalysed in a liquid-liquid two-phase system. The latter comprised a polar catalyst phase of Zn(CF3SO3)2 in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate and a substrate mixture in heptane. The possibility of catalysing different hydroamination reactions continuously was demonstrated.",

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AU - Lercher, Johannes A.

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N2 - The direct addition of NH across a CC multiple bond (hydroamination) was efficiently catalysed in a liquid-liquid two-phase system. The latter comprised a polar catalyst phase of Zn(CF3SO3)2 in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate and a substrate mixture in heptane. The possibility of catalysing different hydroamination reactions continuously was demonstrated.

AB - The direct addition of NH across a CC multiple bond (hydroamination) was efficiently catalysed in a liquid-liquid two-phase system. The latter comprised a polar catalyst phase of Zn(CF3SO3)2 in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate and a substrate mixture in heptane. The possibility of catalysing different hydroamination reactions continuously was demonstrated.

UR - https://www.scopus.com/pages/publications/0037149924

U2 - 10.1039/b111630d

DO - 10.1039/b111630d

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AN - SCOPUS:0037149924

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SP - 906

EP - 907

JO - Chemical Communications

JF - Chemical Communications

IS - 8

ER -

Continuous hydroamination in a liquid-liquid two-phase system

Abstract

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