Complexation of N-heterocyclic silylenes to Pd(0): Formationof highly labile homoleptic complexes Pd[Si(tBuNCH2 CH2NtBu]4 and Pd[Si(tBuNCHCHNtBu)]3

Wolfgang A. Herrmann; Peter Härter; Christian W.K. Gstöttmayr; Frank Bielert; Nicolas Seeboth; Peter Sirsch

doi:10.1016/S0022-328X(02)01110-5

Complexation of N-heterocyclic silylenes to Pd(0): Formationof highly labile homoleptic complexes Pd[Si(^tBuNCH₂ CH₂N^tBu]₄ and Pd[Si(^tBuNCHCHN^tBu)]₃

Wolfgang A. Herrmann, Peter Härter, Christian W.K. Gstöttmayr, Frank Bielert, Nicolas Seeboth, Peter Sirsch

Research output: Contribution to journal › Article › peer-review

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Abstract

The reaction of N-heterocyclic silylenes (NHS) 1 and 2 with Pd complexes, notably [(tert-butyl)₃P]₂Pd(0) and (COD)Pd(CH₃)₂, is described. The formation of homoleptic NHS complexes Pd[Si(^tBuNCH₂CH₂N^tBu)]₄ and Pd[Si(^tBuNCHCHN^tBu)]₃ is reported. The rearrangement of these complexes into dinuclear silylene-bridged compounds and the solid state structures of the latter complexes are discussed.

Original language	English
Pages (from-to)	141-146
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	649
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(02)01110-5
State	Published - 22 Apr 2002

Keywords

N-heterocyclic silylenes
Pd complexes
X-ray structures
μ-silylene complexes

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10.1016/S0022-328X(02)01110-5

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title = "Complexation of N-heterocyclic silylenes to Pd(0): Formationof highly labile homoleptic complexes Pd[Si(tBuNCH2 CH2NtBu]4 and Pd[Si(tBuNCHCHNtBu)]3",

abstract = "The reaction of N-heterocyclic silylenes (NHS) 1 and 2 with Pd complexes, notably [(tert-butyl)3P]2Pd(0) and (COD)Pd(CH3)2, is described. The formation of homoleptic NHS complexes Pd[Si(tBuNCH2CH2NtBu)]4 and Pd[Si(tBuNCHCHNtBu)]3 is reported. The rearrangement of these complexes into dinuclear silylene-bridged compounds and the solid state structures of the latter complexes are discussed.",

keywords = "N-heterocyclic silylenes, Pd complexes, X-ray structures, μ-silylene complexes",

author = "Herrmann, \{Wolfgang A.\} and Peter H{\"a}rter and Gst{\"o}ttmayr, \{Christian W.K.\} and Frank Bielert and Nicolas Seeboth and Peter Sirsch",

year = "2002",

month = apr,

day = "22",

doi = "10.1016/S0022-328X(02)01110-5",

language = "English",

volume = "649",

pages = "141--146",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

}

Complexation of N-heterocyclic silylenes to Pd(0): Formationof highly labile homoleptic complexes Pd[Si(^tBuNCH₂ CH₂N^tBu]₄ and Pd[Si(^tBuNCHCHN^tBu)]₃. / Herrmann, Wolfgang A.; Härter, Peter; Gstöttmayr, Christian W.K. et al.
In: Journal of Organometallic Chemistry, Vol. 649, No. 2, 22.04.2002, p. 141-146.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Complexation of N-heterocyclic silylenes to Pd(0)

T2 - Formationof highly labile homoleptic complexes Pd[Si(tBuNCH2 CH2NtBu]4 and Pd[Si(tBuNCHCHNtBu)]3

AU - Herrmann, Wolfgang A.

AU - Härter, Peter

AU - Gstöttmayr, Christian W.K.

AU - Bielert, Frank

AU - Seeboth, Nicolas

AU - Sirsch, Peter

PY - 2002/4/22

Y1 - 2002/4/22

N2 - The reaction of N-heterocyclic silylenes (NHS) 1 and 2 with Pd complexes, notably [(tert-butyl)3P]2Pd(0) and (COD)Pd(CH3)2, is described. The formation of homoleptic NHS complexes Pd[Si(tBuNCH2CH2NtBu)]4 and Pd[Si(tBuNCHCHNtBu)]3 is reported. The rearrangement of these complexes into dinuclear silylene-bridged compounds and the solid state structures of the latter complexes are discussed.

AB - The reaction of N-heterocyclic silylenes (NHS) 1 and 2 with Pd complexes, notably [(tert-butyl)3P]2Pd(0) and (COD)Pd(CH3)2, is described. The formation of homoleptic NHS complexes Pd[Si(tBuNCH2CH2NtBu)]4 and Pd[Si(tBuNCHCHNtBu)]3 is reported. The rearrangement of these complexes into dinuclear silylene-bridged compounds and the solid state structures of the latter complexes are discussed.

KW - N-heterocyclic silylenes

KW - Pd complexes

KW - X-ray structures

KW - μ-silylene complexes

UR - http://www.scopus.com/inward/record.url?scp=0037156326&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(02)01110-5

DO - 10.1016/S0022-328X(02)01110-5

M3 - Article

AN - SCOPUS:0037156326

SN - 0022-328X

VL - 649

SP - 141

EP - 146

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Complexation of N-heterocyclic silylenes to Pd(0): Formationof highly labile homoleptic complexes Pd[Si(^tBuNCH₂ CH₂N^tBu]₄ and Pd[Si(^tBuNCHCHN^tBu)]₃

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