Coinage metal complexes of NHC-stabilized silyliumylidene ions

Philipp Frisch; Shigeyoshi Inoue

doi:10.1039/c8cc07754a

Coinage metal complexes of NHC-stabilized silyliumylidene ions

Philipp Frisch
, Shigeyoshi Inoue

Chair of Silicon Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me₂S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.

Original language	English
Pages (from-to)	13658-13661
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	97
DOIs	https://doi.org/10.1039/c8cc07754a
State	Published - 2018

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title = "Coinage metal complexes of NHC-stabilized silyliumylidene ions",

abstract = "The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.",

author = "Philipp Frisch and Shigeyoshi Inoue",

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year = "2018",

doi = "10.1039/c8cc07754a",

language = "English",

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pages = "13658--13661",

journal = "Chemical Communications",

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AU - Frisch, Philipp

AU - Inoue, Shigeyoshi

PY - 2018

Y1 - 2018

N2 - The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.

AB - The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.

UR - https://www.scopus.com/pages/publications/85058171456

U2 - 10.1039/c8cc07754a

DO - 10.1039/c8cc07754a

M3 - Article

C2 - 30357178

AN - SCOPUS:85058171456

SN - 1359-7345

VL - 54

SP - 13658

EP - 13661

JO - Chemical Communications

JF - Chemical Communications

IS - 97

ER -

Coinage metal complexes of NHC-stabilized silyliumylidene ions

Abstract

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