Coinage metal complexes of NHC-stabilized silyliumylidene ions

Philipp Frisch; Shigeyoshi Inoue

doi:10.1039/c8cc07754a

Coinage metal complexes of NHC-stabilized silyliumylidene ions

Philipp Frisch, Shigeyoshi Inoue

Chair of Silicon Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me₂S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.

Original language	English
Pages (from-to)	13658-13661
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	97
DOIs	https://doi.org/10.1039/c8cc07754a
State	Published - 2018

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abstract = "The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.",

author = "Philipp Frisch and Shigeyoshi Inoue",

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AU - Inoue, Shigeyoshi

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AB - The first silyliumylidene ion coinage metal complexes are reported. Treatment of N-heterocyclic carbene (NHC) stabilized silyliumylidene ions (R = m-Ter, Tipp) with transition metal precursors (CuCl, AgOTf, (Me2S)AuCl) yields the first silyliumylidene coinage metal (M = Cu, Ag, Au) complexes, which have been fully characterized including X-ray diffraction analyses.

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JO - Chemical Communications

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ER -

Coinage metal complexes of NHC-stabilized silyliumylidene ions

Abstract

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