Co and Mn polysiloxanes as unique initiator-catalyst-systems for the selective liquid phase oxidation of o-xylene

Tobias Förster; Stephan A. Schunk; Andreas Jentys; Johannes A. Lercher

doi:10.1039/c0cc05050d

Co and Mn polysiloxanes as unique initiator-catalyst-systems for the selective liquid phase oxidation of o-xylene

Tobias Förster, Stephan A. Schunk, Andreas Jentys, Johannes A. Lercher

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Co and Mn polysiloxanes are unique catalyst/initiator systems for the liquid phase oxidation of o-xylene showing higher activity than Co naphthenates, which is related to the weak interaction of the polar products with the hydrophobic surface as well as the absence of hydroxyl groups and surrounding oxygenates limiting radical quenching.

Original language	English
Pages (from-to)	3254-3256
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	11
DOIs	https://doi.org/10.1039/c0cc05050d
State	Published - 1 Mar 2011

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title = "Co and Mn polysiloxanes as unique initiator-catalyst-systems for the selective liquid phase oxidation of o-xylene",

abstract = "Co and Mn polysiloxanes are unique catalyst/initiator systems for the liquid phase oxidation of o-xylene showing higher activity than Co naphthenates, which is related to the weak interaction of the polar products with the hydrophobic surface as well as the absence of hydroxyl groups and surrounding oxygenates limiting radical quenching.",

author = "Tobias F{\"o}rster and Schunk, {Stephan A.} and Andreas Jentys and Lercher, {Johannes A.}",

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T1 - Co and Mn polysiloxanes as unique initiator-catalyst-systems for the selective liquid phase oxidation of o-xylene

AU - Förster, Tobias

AU - Schunk, Stephan A.

AU - Jentys, Andreas

AU - Lercher, Johannes A.

PY - 2011/3/1

Y1 - 2011/3/1

N2 - Co and Mn polysiloxanes are unique catalyst/initiator systems for the liquid phase oxidation of o-xylene showing higher activity than Co naphthenates, which is related to the weak interaction of the polar products with the hydrophobic surface as well as the absence of hydroxyl groups and surrounding oxygenates limiting radical quenching.

AB - Co and Mn polysiloxanes are unique catalyst/initiator systems for the liquid phase oxidation of o-xylene showing higher activity than Co naphthenates, which is related to the weak interaction of the polar products with the hydrophobic surface as well as the absence of hydroxyl groups and surrounding oxygenates limiting radical quenching.

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U2 - 10.1039/c0cc05050d

DO - 10.1039/c0cc05050d

M3 - Article

AN - SCOPUS:79952833785

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VL - 47

SP - 3254

EP - 3256

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Co and Mn polysiloxanes as unique initiator-catalyst-systems for the selective liquid phase oxidation of o-xylene

Abstract

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