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Cluster surface interactions: Small Fe clusters driven nonmagnetic on graphite

  • K. Fauth
  • , S. Gold
  • , M. Heßler
  • , N. Schneider
  • , G. Schütz
  • University of Würzburg
  • Max Planck Institute for Intelligent Systems

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

We present a study of the changes in the magnetic and electronic properties of small, deposited Fe clusters upon exposure to the graphite surface. The clusters exhibit strong X-ray magnetic circular dichroism (XMCD) at the L 3 edge while matrix isolated in a thin Ar film. XMCD and photoemission experiments show that the clusters are driven into a nonmagnetic state by the interaction to graphite. Our results support earlier calculations for adatoms and dimers and extend their validity to larger cluster sizes. They also provide a basis for an understanding of the magnetic properties of carbon encapsulated transition metal particles.

Original languageEnglish
Pages (from-to)498-502
Number of pages5
JournalChemical Physics Letters
Volume392
Issue number4-6
DOIs
StatePublished - 11 Jul 2004
Externally publishedYes

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