Chemistry of the H3B(CH3)2P Group: Unusual Properties of Some Simple Reference Compounds

Hubert Schmidbaur, Erwin Weiss

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

The analogy between the isoelectronic groups Me3Si and Me2(H3B)P exists not only on paper. For example, the Me3SiCl analogue 1 is stable, distillable and relatively insensitive to moisture; on treatment with Ag2O it affords the air‐ and water‐stable compound 2 corresponding to disiloxane. (Figure Presented.)

Original languageEnglish
Pages (from-to)781-782
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume18
Issue number10
DOIs
StatePublished - Oct 1979
Externally publishedYes

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