Chelating N-heterocyclic carbene ligands in palladium-catalyzed heck-type reactions

Wolfgang A. Herrmann; Claus Peter Reisinger; Michael Spiegler

doi:10.1016/S0022-328X(97)00736-5

Chelating N-heterocyclic carbene ligands in palladium-catalyzed heck-type reactions

Wolfgang A. Herrmann, Claus Peter Reisinger, Michael Spiegler

Technical University of Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

574 Scopus citations

Abstract

A novel synthesis of palladium complexes with chelating N-heterocyclic carbene ligands is reported and direct proof is presented by X-ray diffraction. These catalyst precursors are efficiently applied in palladium-catalyzed Heck-, Suzuki- and alkyne coupling reactions, demonstrating the versatility of our ligand concept in homogeneous catalysis.

Original language	English
Pages (from-to)	93-96
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	557
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(97)00736-5
State	Published - 20 Apr 1998

Keywords

Coupling reactions
N-heterocyclic
Palladium complexes

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10.1016/S0022-328X(97)00736-5

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title = "Chelating N-heterocyclic carbene ligands in palladium-catalyzed heck-type reactions",

abstract = "A novel synthesis of palladium complexes with chelating N-heterocyclic carbene ligands is reported and direct proof is presented by X-ray diffraction. These catalyst precursors are efficiently applied in palladium-catalyzed Heck-, Suzuki- and alkyne coupling reactions, demonstrating the versatility of our ligand concept in homogeneous catalysis.",

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AU - A. Herrmann, Wolfgang

AU - Reisinger, Claus Peter

AU - Spiegler, Michael

PY - 1998/4/20

Y1 - 1998/4/20

N2 - A novel synthesis of palladium complexes with chelating N-heterocyclic carbene ligands is reported and direct proof is presented by X-ray diffraction. These catalyst precursors are efficiently applied in palladium-catalyzed Heck-, Suzuki- and alkyne coupling reactions, demonstrating the versatility of our ligand concept in homogeneous catalysis.

AB - A novel synthesis of palladium complexes with chelating N-heterocyclic carbene ligands is reported and direct proof is presented by X-ray diffraction. These catalyst precursors are efficiently applied in palladium-catalyzed Heck-, Suzuki- and alkyne coupling reactions, demonstrating the versatility of our ligand concept in homogeneous catalysis.

KW - Coupling reactions

KW - N-heterocyclic

KW - Palladium complexes

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U2 - 10.1016/S0022-328X(97)00736-5

DO - 10.1016/S0022-328X(97)00736-5

M3 - Article

AN - SCOPUS:0002442679

SN - 0022-328X

VL - 557

SP - 93

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Chelating N-heterocyclic carbene ligands in palladium-catalyzed heck-type reactions

Abstract

Keywords

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