Characterization of Tl-rare gas complexes and comparison with other group 3A metal complexes

A. Stangassinger; J. Scheuchenpflug; T. Prinz; V. E. Bondybey

doi:10.1016/0301-0104(93)85090-U

Characterization of Tl-rare gas complexes and comparison with other group 3A metal complexes

A. Stangassinger
, J. Scheuchenpflug
, T. Prinz
, V. E. Bondybey

Chair of Physical Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The TlAr, TlKr, and TlXe complexes have been produced by sputtering of a Tl electrode, and detected in a supersonic jet expansion by laser excitation spectroscopy. Analysis of the B ²Σ⁺←X ²Π_{1 2} and B ²Σ⁺←X ²Π_{3 2} transitions yields information about the vibrational potential and binding energies of the complexes. Their molecular constants are reported and the results are compared with other group 3A metals. Comparisons and trends within the group are discussed.

Original language	English
Pages (from-to)	533-546
Number of pages	14
Journal	Chemical Physics
Volume	178
Issue number	1-3
DOIs	https://doi.org/10.1016/0301-0104(93)85090-U
State	Published - 15 Dec 1993

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abstract = "The TlAr, TlKr, and TlXe complexes have been produced by sputtering of a Tl electrode, and detected in a supersonic jet expansion by laser excitation spectroscopy. Analysis of the B 2Σ+←X 2Π 1 2 and B 2Σ+←X 2Π 3 2 transitions yields information about the vibrational potential and binding energies of the complexes. Their molecular constants are reported and the results are compared with other group 3A metals. Comparisons and trends within the group are discussed.",

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AU - Stangassinger, A.

AU - Scheuchenpflug, J.

AU - Prinz, T.

AU - Bondybey, V. E.

PY - 1993/12/15

Y1 - 1993/12/15

N2 - The TlAr, TlKr, and TlXe complexes have been produced by sputtering of a Tl electrode, and detected in a supersonic jet expansion by laser excitation spectroscopy. Analysis of the B 2Σ+←X 2Π 1 2 and B 2Σ+←X 2Π 3 2 transitions yields information about the vibrational potential and binding energies of the complexes. Their molecular constants are reported and the results are compared with other group 3A metals. Comparisons and trends within the group are discussed.

AB - The TlAr, TlKr, and TlXe complexes have been produced by sputtering of a Tl electrode, and detected in a supersonic jet expansion by laser excitation spectroscopy. Analysis of the B 2Σ+←X 2Π 1 2 and B 2Σ+←X 2Π 3 2 transitions yields information about the vibrational potential and binding energies of the complexes. Their molecular constants are reported and the results are compared with other group 3A metals. Comparisons and trends within the group are discussed.

UR - https://www.scopus.com/pages/publications/21344479674

U2 - 10.1016/0301-0104(93)85090-U

DO - 10.1016/0301-0104(93)85090-U

M3 - Article

AN - SCOPUS:21344479674

SN - 0301-0104

VL - 178

SP - 533

EP - 546

JO - Chemical Physics

JF - Chemical Physics

IS - 1-3

ER -

Characterization of Tl-rare gas complexes and comparison with other group 3A metal complexes

Abstract

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