Catena-Poly[[(tetrahydrofuran-jO)-potassium]-l-(n5:n 5)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]

Rüdiger W. Seidel; Chelladurai Ganesamoorthy; Sinah Loerke; Manuela V. Winter; Christian Gemel; Roland A. Fischer

doi:10.1107/S0108270113011074

Catena-Poly[[(tetrahydrofuran-jO)-potassium]-l-(n⁵:n ⁵)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]

Rüdiger W. Seidel
, Chelladurai Ganesamoorthy
, Sinah Loerke
, Manuela V. Winter
, Christian Gemel
, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, [K(C₁₄H₂₃)(C₄H ₈O)]_n, comprises zigzag chains of alternating bridging 2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl ligands and potassium ions, with an ancillary tetrahydrofuran ligand in the coordination environment of potassium. The coordination polymer strands so formed extend by 2₁ screw symmetry in the b-axis direction. The chemically modified cyclopentadienyl ligand, with a tethered n-pentyl group, was synthesized from 2,3,4,5-tetramethylcyclopent-2-enone by a Grignard reaction.

Original language	English
Pages (from-to)	573-576
Number of pages	4
Journal	Acta Crystallographica Section C
Volume	69
Issue number	6
DOIs	https://doi.org/10.1107/S0108270113011074
State	Published - 2013
Externally published	Yes

Access to Document

10.1107/S0108270113011074

Cite this

@article{4f23d6fac32d42bab158e1cbb021c620,

title = "Catena-Poly[[(tetrahydrofuran-jO)-potassium]-l-(n5:n 5)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]",

abstract = "The title compound, [K(C14H23)(C4H 8O)]n, comprises zigzag chains of alternating bridging 2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl ligands and potassium ions, with an ancillary tetrahydrofuran ligand in the coordination environment of potassium. The coordination polymer strands so formed extend by 21 screw symmetry in the b-axis direction. The chemically modified cyclopentadienyl ligand, with a tethered n-pentyl group, was synthesized from 2,3,4,5-tetramethylcyclopent-2-enone by a Grignard reaction.",

author = "Seidel, \{R{\"u}diger W.\} and Chelladurai Ganesamoorthy and Sinah Loerke and Winter, \{Manuela V.\} and Christian Gemel and Fischer, \{Roland A.\}",

year = "2013",

doi = "10.1107/S0108270113011074",

language = "English",

volume = "69",

pages = "573--576",

journal = "Acta Crystallographica Section C",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "6",

}

TY - JOUR

T1 - Catena-Poly[[(tetrahydrofuran-jO)-potassium]-l-(n5:n 5)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]

AU - Seidel, Rüdiger W.

AU - Ganesamoorthy, Chelladurai

AU - Loerke, Sinah

AU - Winter, Manuela V.

AU - Gemel, Christian

AU - Fischer, Roland A.

PY - 2013

Y1 - 2013

N2 - The title compound, [K(C14H23)(C4H 8O)]n, comprises zigzag chains of alternating bridging 2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl ligands and potassium ions, with an ancillary tetrahydrofuran ligand in the coordination environment of potassium. The coordination polymer strands so formed extend by 21 screw symmetry in the b-axis direction. The chemically modified cyclopentadienyl ligand, with a tethered n-pentyl group, was synthesized from 2,3,4,5-tetramethylcyclopent-2-enone by a Grignard reaction.

AB - The title compound, [K(C14H23)(C4H 8O)]n, comprises zigzag chains of alternating bridging 2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl ligands and potassium ions, with an ancillary tetrahydrofuran ligand in the coordination environment of potassium. The coordination polymer strands so formed extend by 21 screw symmetry in the b-axis direction. The chemically modified cyclopentadienyl ligand, with a tethered n-pentyl group, was synthesized from 2,3,4,5-tetramethylcyclopent-2-enone by a Grignard reaction.

UR - https://www.scopus.com/pages/publications/84878869603

U2 - 10.1107/S0108270113011074

DO - 10.1107/S0108270113011074

M3 - Article

AN - SCOPUS:84878869603

SN - 0108-2701

VL - 69

SP - 573

EP - 576

JO - Acta Crystallographica Section C

JF - Acta Crystallographica Section C

IS - 6

ER -

Catena-Poly[[(tetrahydrofuran-jO)-potassium]-l-(n⁵:n ⁵)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]

Abstract

Access to Document

Other files and links

Fingerprint

Cite this