TY - JOUR
T1 - Catena-Poly[[(tetrahydrofuran-jO)-potassium]-l-(n5:n 5)-2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl]
AU - Seidel, Rüdiger W.
AU - Ganesamoorthy, Chelladurai
AU - Loerke, Sinah
AU - Winter, Manuela V.
AU - Gemel, Christian
AU - Fischer, Roland A.
PY - 2013
Y1 - 2013
N2 - The title compound, [K(C14H23)(C4H 8O)]n, comprises zigzag chains of alternating bridging 2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl ligands and potassium ions, with an ancillary tetrahydrofuran ligand in the coordination environment of potassium. The coordination polymer strands so formed extend by 21 screw symmetry in the b-axis direction. The chemically modified cyclopentadienyl ligand, with a tethered n-pentyl group, was synthesized from 2,3,4,5-tetramethylcyclopent-2-enone by a Grignard reaction.
AB - The title compound, [K(C14H23)(C4H 8O)]n, comprises zigzag chains of alternating bridging 2,3,4,5-tetramethyl-1-n-pentylcyclopentadienyl ligands and potassium ions, with an ancillary tetrahydrofuran ligand in the coordination environment of potassium. The coordination polymer strands so formed extend by 21 screw symmetry in the b-axis direction. The chemically modified cyclopentadienyl ligand, with a tethered n-pentyl group, was synthesized from 2,3,4,5-tetramethylcyclopent-2-enone by a Grignard reaction.
UR - http://www.scopus.com/inward/record.url?scp=84878869603&partnerID=8YFLogxK
U2 - 10.1107/S0108270113011074
DO - 10.1107/S0108270113011074
M3 - Article
AN - SCOPUS:84878869603
SN - 0108-2701
VL - 69
SP - 573
EP - 576
JO - Acta Crystallographica Section C
JF - Acta Crystallographica Section C
IS - 6
ER -