TY - JOUR
T1 - Catalytic enantioselective fluorination of β-ketoesters
AU - Hintermann, Lukas
AU - Togni, Antonio
PY - 2000/12/4
Y1 - 2000/12/4
N2 - Isolated and crystallized [Ti(TADDOLato)] complexes were used as catalysts for the first catalytic enantioselective (up to 90 % ee) C-F bond-forming reaction, the fluorination of β-ketoesters with the N-fluorotriethylenediammonium salt F-TEDA [Eq. (1)]. TADDOL=2,2-dimethyl-α,α,α',α'-tetraaryl-1,3-dioxolan-4,5-dimethanol.
AB - Isolated and crystallized [Ti(TADDOLato)] complexes were used as catalysts for the first catalytic enantioselective (up to 90 % ee) C-F bond-forming reaction, the fluorination of β-ketoesters with the N-fluorotriethylenediammonium salt F-TEDA [Eq. (1)]. TADDOL=2,2-dimethyl-α,α,α',α'-tetraaryl-1,3-dioxolan-4,5-dimethanol.
KW - Asymmetric catalysis
KW - Fluorine
KW - TADDOL
KW - Titanium
UR - http://www.scopus.com/inward/record.url?scp=0034605873&partnerID=8YFLogxK
U2 - 10.1002/1521-3773(20001201)39:23<4359::AID-ANIE4359>3.0.CO;2-P
DO - 10.1002/1521-3773(20001201)39:23<4359::AID-ANIE4359>3.0.CO;2-P
M3 - Article
AN - SCOPUS:0034605873
SN - 1433-7851
VL - 39
SP - 4359
EP - 4362
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 23
ER -