Catalytic Enantioselective CC Coupling—Allyl Transfer and Mukaiyama Aldol Reaction

Thorsten Bach

doi:10.1002/anie.199404171

Catalytic Enantioselective CC Coupling—Allyl Transfer and Mukaiyama Aldol Reaction

Thorsten Bach

University of Münster

Research output: Contribution to journal › Article › peer-review

163 Scopus citations

Abstract

To obtain enantiomerically pure products without using stoichiometric quantities of chiral components is now possible for the title reactions [Eq. (a)]. Chiral Lewis acids M′X_n are employed, which enable an excellent facial differentiation. In some cases these catalysts provide enantiomeric excesses greater than 95% and outstanding chemical yields. (Figure Presented.)

Original language	English
Pages (from-to)	417-419
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	33
Issue number	4
DOIs	https://doi.org/10.1002/anie.199404171
State	Published - 3 Mar 1994
Externally published	Yes

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@article{9ec5fd7cb3d3488eb896f18b5cfb5248,

title = "Catalytic Enantioselective CC Coupling—Allyl Transfer and Mukaiyama Aldol Reaction",

abstract = "To obtain enantiomerically pure products without using stoichiometric quantities of chiral components is now possible for the title reactions [Eq. (a)]. Chiral Lewis acids M′Xn are employed, which enable an excellent facial differentiation. In some cases these catalysts provide enantiomeric excesses greater than 95\% and outstanding chemical yields. (Figure Presented.)",

author = "Thorsten Bach",

year = "1994",

month = mar,

day = "3",

doi = "10.1002/anie.199404171",

language = "English",

volume = "33",

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journal = "Angewandte Chemie International Edition in English",

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TY - JOUR

T1 - Catalytic Enantioselective CC Coupling—Allyl Transfer and Mukaiyama Aldol Reaction

AU - Bach, Thorsten

PY - 1994/3/3

Y1 - 1994/3/3

N2 - To obtain enantiomerically pure products without using stoichiometric quantities of chiral components is now possible for the title reactions [Eq. (a)]. Chiral Lewis acids M′Xn are employed, which enable an excellent facial differentiation. In some cases these catalysts provide enantiomeric excesses greater than 95% and outstanding chemical yields. (Figure Presented.)

AB - To obtain enantiomerically pure products without using stoichiometric quantities of chiral components is now possible for the title reactions [Eq. (a)]. Chiral Lewis acids M′Xn are employed, which enable an excellent facial differentiation. In some cases these catalysts provide enantiomeric excesses greater than 95% and outstanding chemical yields. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/33748238772

U2 - 10.1002/anie.199404171

DO - 10.1002/anie.199404171

M3 - Article

AN - SCOPUS:33748238772

SN - 0570-0833

VL - 33

SP - 417

EP - 419

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 4

ER -

Catalytic Enantioselective CC Coupling—Allyl Transfer and Mukaiyama Aldol Reaction

Abstract

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