“Carbodiphosphoranes” by a New Rearrangement of Phosphorus Ylides

Anette Wohlleben; Hubert Schmidbaur

doi:10.1002/anie.197704171

“Carbodiphosphoranes” by a New Rearrangement of Phosphorus Ylides

Anette Wohlleben
, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

An unexpected reaction of methylenebisphosphonium salts such as 1 is their rearrangement to “carbodiphosphoranes” 2 on deprotonation. The bisphosphorane 3 is not formed. (Figure Presented.)

Original language	English
Pages (from-to)	417-418
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	16
Issue number	6
DOIs	https://doi.org/10.1002/anie.197704171
State	Published - Jun 1977

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title = "“Carbodiphosphoranes” by a New Rearrangement of Phosphorus Ylides",

abstract = "An unexpected reaction of methylenebisphosphonium salts such as 1 is their rearrangement to “carbodiphosphoranes” 2 on deprotonation. The bisphosphorane 3 is not formed. (Figure Presented.)",

author = "Anette Wohlleben and Hubert Schmidbaur",

year = "1977",

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AB - An unexpected reaction of methylenebisphosphonium salts such as 1 is their rearrangement to “carbodiphosphoranes” 2 on deprotonation. The bisphosphorane 3 is not formed. (Figure Presented.)

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M3 - Article

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

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“Carbodiphosphoranes” by a New Rearrangement of Phosphorus Ylides

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