TY - JOUR
T1 - Carbocyclic carbene ligands in palladium-catalyzed C-N coupling reactions
AU - Taubmann, Christian
AU - Tosh, Evangeline
AU - Öfele, Karl
AU - Herdtweck, Eberhardt
AU - Herrmann, Wolfgang A.
PY - 2008/6/15
Y1 - 2008/6/15
N2 - Palladium complexes bearing a cycloheptatrienylidene ligand are powerful precatalysts for C-N coupling reactions. Their catalytic performance is directly compared to analogous 2,3-diphenylcyclopropenylidene complexes. The crystal structure of cis-dibromo(cycloheptatrienylidene)(triphenylphosphane)palladium(II) is presented.
AB - Palladium complexes bearing a cycloheptatrienylidene ligand are powerful precatalysts for C-N coupling reactions. Their catalytic performance is directly compared to analogous 2,3-diphenylcyclopropenylidene complexes. The crystal structure of cis-dibromo(cycloheptatrienylidene)(triphenylphosphane)palladium(II) is presented.
KW - C-N coupling
KW - Carbenes
KW - Carbocycles
KW - Homogeneous catalysis
KW - Palladium
UR - http://www.scopus.com/inward/record.url?scp=44649098847&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2008.03.016
DO - 10.1016/j.jorganchem.2008.03.016
M3 - Article
AN - SCOPUS:44649098847
SN - 0022-328X
VL - 693
SP - 2231
EP - 2236
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 13
ER -