Carbocyclic carbene ligands in palladium-catalyzed C-N coupling reactions

Christian Taubmann; Evangeline Tosh; Karl Öfele; Eberhardt Herdtweck; Wolfgang A. Herrmann

doi:10.1016/j.jorganchem.2008.03.016

Carbocyclic carbene ligands in palladium-catalyzed C-N coupling reactions

Christian Taubmann, Evangeline Tosh, Karl Öfele, Eberhardt Herdtweck, Wolfgang A. Herrmann

Technical University of Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

Palladium complexes bearing a cycloheptatrienylidene ligand are powerful precatalysts for C-N coupling reactions. Their catalytic performance is directly compared to analogous 2,3-diphenylcyclopropenylidene complexes. The crystal structure of cis-dibromo(cycloheptatrienylidene)(triphenylphosphane)palladium(II) is presented.

Original language	English
Pages (from-to)	2231-2236
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	693
Issue number	13
DOIs	https://doi.org/10.1016/j.jorganchem.2008.03.016
State	Published - 15 Jun 2008

Keywords

C-N coupling
Carbenes
Carbocycles
Homogeneous catalysis
Palladium

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10.1016/j.jorganchem.2008.03.016

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title = "Carbocyclic carbene ligands in palladium-catalyzed C-N coupling reactions",

abstract = "Palladium complexes bearing a cycloheptatrienylidene ligand are powerful precatalysts for C-N coupling reactions. Their catalytic performance is directly compared to analogous 2,3-diphenylcyclopropenylidene complexes. The crystal structure of cis-dibromo(cycloheptatrienylidene)(triphenylphosphane)palladium(II) is presented.",

keywords = "C-N coupling, Carbenes, Carbocycles, Homogeneous catalysis, Palladium",

author = "Christian Taubmann and Evangeline Tosh and Karl {\"O}fele and Eberhardt Herdtweck and Herrmann, {Wolfgang A.}",

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T1 - Carbocyclic carbene ligands in palladium-catalyzed C-N coupling reactions

AU - Taubmann, Christian

AU - Tosh, Evangeline

AU - Öfele, Karl

AU - Herdtweck, Eberhardt

AU - Herrmann, Wolfgang A.

PY - 2008/6/15

Y1 - 2008/6/15

N2 - Palladium complexes bearing a cycloheptatrienylidene ligand are powerful precatalysts for C-N coupling reactions. Their catalytic performance is directly compared to analogous 2,3-diphenylcyclopropenylidene complexes. The crystal structure of cis-dibromo(cycloheptatrienylidene)(triphenylphosphane)palladium(II) is presented.

AB - Palladium complexes bearing a cycloheptatrienylidene ligand are powerful precatalysts for C-N coupling reactions. Their catalytic performance is directly compared to analogous 2,3-diphenylcyclopropenylidene complexes. The crystal structure of cis-dibromo(cycloheptatrienylidene)(triphenylphosphane)palladium(II) is presented.

KW - C-N coupling

KW - Carbenes

KW - Carbocycles

KW - Homogeneous catalysis

KW - Palladium

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U2 - 10.1016/j.jorganchem.2008.03.016

DO - 10.1016/j.jorganchem.2008.03.016

M3 - Article

AN - SCOPUS:44649098847

SN - 0022-328X

VL - 693

SP - 2231

EP - 2236

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 13

ER -

Carbocyclic carbene ligands in palladium-catalyzed C-N coupling reactions

Abstract

Keywords

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