C-H activated isomers of [M(AlCp*)5] (M=Fe, Ru)

Tobias Steinke; Mirza Cokoja; Christian Gemel; Andreas Kempter; Andreas Krapp; Gernot Frenking; Ulrich Zenneck; Roland A. Fischer

doi:10.1002/anie.200462834

C-H activated isomers of [M(AlCp*)₅] (M=Fe, Ru)

Tobias Steinke
, Mirza Cokoja
, Christian Gemel
, Andreas Kempter
, Andreas Krapp
, Gernot Frenking
, Ulrich Zenneck
, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung
Philipps-Universität Marburg
Friedrich Alexander Universität Erlangen-Nürnberg

Research output: Contribution to journal › Article › peer-review

73 Scopus citations

Abstract

(Figure Presented) What are the limits for n in the case of [M(E ^lR)_n] (M = transition metal; E = Al, Ga, In)? Is n = 5 possible, maybe n = 6, or even more? A first insight is gained through the reactions of Fe⁰ and Ru⁰ precursors with excess of AlCp*, leading to C-H activated isomers of [M(AlCp*)₅] (see picture for M = Fe, gray C, white H, blue Al, red Fe, Cp* = C ₅Me₅).

Original language	English
Pages (from-to)	2943-2946
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	44
Issue number	19
DOIs	https://doi.org/10.1002/anie.200462834
State	Published - 6 May 2005
Externally published	Yes

Keywords

Aluminum
C-H activation
Carbenoids
Iron
Ruthenium

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abstract = "(Figure Presented) What are the limits for n in the case of [M(E lR)n] (M = transition metal; E = Al, Ga, In)? Is n = 5 possible, maybe n = 6, or even more? A first insight is gained through the reactions of Fe0 and Ru0 precursors with excess of AlCp*, leading to C-H activated isomers of [M(AlCp*)5] (see picture for M = Fe, gray C, white H, blue Al, red Fe, Cp* = C 5Me5).",

keywords = "Aluminum, C-H activation, Carbenoids, Iron, Ruthenium",

author = "Tobias Steinke and Mirza Cokoja and Christian Gemel and Andreas Kempter and Andreas Krapp and Gernot Frenking and Ulrich Zenneck and Fischer, \{Roland A.\}",

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T1 - C-H activated isomers of [M(AlCp*)5] (M=Fe, Ru)

AU - Steinke, Tobias

AU - Cokoja, Mirza

AU - Gemel, Christian

AU - Kempter, Andreas

AU - Krapp, Andreas

AU - Frenking, Gernot

AU - Zenneck, Ulrich

AU - Fischer, Roland A.

PY - 2005/5/6

Y1 - 2005/5/6

N2 - (Figure Presented) What are the limits for n in the case of [M(E lR)n] (M = transition metal; E = Al, Ga, In)? Is n = 5 possible, maybe n = 6, or even more? A first insight is gained through the reactions of Fe0 and Ru0 precursors with excess of AlCp*, leading to C-H activated isomers of [M(AlCp*)5] (see picture for M = Fe, gray C, white H, blue Al, red Fe, Cp* = C 5Me5).

AB - (Figure Presented) What are the limits for n in the case of [M(E lR)n] (M = transition metal; E = Al, Ga, In)? Is n = 5 possible, maybe n = 6, or even more? A first insight is gained through the reactions of Fe0 and Ru0 precursors with excess of AlCp*, leading to C-H activated isomers of [M(AlCp*)5] (see picture for M = Fe, gray C, white H, blue Al, red Fe, Cp* = C 5Me5).

KW - Aluminum

KW - C-H activation

KW - Carbenoids

KW - Iron

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/18844362940

U2 - 10.1002/anie.200462834

DO - 10.1002/anie.200462834

M3 - Article

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AN - SCOPUS:18844362940

SN - 1433-7851

VL - 44

SP - 2943

EP - 2946

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 19

ER -

C-H activated isomers of [M(AlCp*)₅] (M=Fe, Ru)

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Keywords

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