Broadband inversion PELDOR spectroscopy with partially adiabatic shaped pulses

Philipp E. Spindler; Steffen J. Glaser; Thomas E. Skinner; Thomas F. Prisner

doi:10.1002/anie.201207777

Broadband inversion PELDOR spectroscopy with partially adiabatic shaped pulses

Philipp E. Spindler
, Steffen J. Glaser
, Thomas E. Skinner
, Thomas F. Prisner

Associate Professorship of Organic Chemistry

Johann Wolfgang Goethe University
Wright State University

Research output: Contribution to journal › Article › peer-review

119 Scopus citations

Abstract

Distance and spins: A new broadband, frequency-selective inversion pulse has been devised for pulsed electron-electron double resonance (PELDOR) spectroscopy, a unique method used to determine distance distributions between two or more paramagnetic centers 2-10 nm apart. The PELDOR modulation depth can be increased by substituting the rectangular pump pulse by a shaped pulse.

Original language	English
Pages (from-to)	3425-3429
Number of pages	5
Journal	Angewandte Chemie International Edition in English
Volume	52
Issue number	12
DOIs	https://doi.org/10.1002/anie.201207777
State	Published - 18 Mar 2013

Keywords

EPR spectroscopy
PELDOR
adiabatic pulses
broadband inversion pulses
transition-metal ions

Access to Document

10.1002/anie.201207777

Cite this

@article{84634a20255745dfa0541b3d37794228,

title = "Broadband inversion PELDOR spectroscopy with partially adiabatic shaped pulses",

abstract = "Distance and spins: A new broadband, frequency-selective inversion pulse has been devised for pulsed electron-electron double resonance (PELDOR) spectroscopy, a unique method used to determine distance distributions between two or more paramagnetic centers 2-10 nm apart. The PELDOR modulation depth can be increased by substituting the rectangular pump pulse by a shaped pulse.",

keywords = "EPR spectroscopy, PELDOR, adiabatic pulses, broadband inversion pulses, transition-metal ions",

author = "Spindler, \{Philipp E.\} and Glaser, \{Steffen J.\} and Skinner, \{Thomas E.\} and Prisner, \{Thomas F.\}",

year = "2013",

month = mar,

day = "18",

doi = "10.1002/anie.201207777",

language = "English",

volume = "52",

pages = "3425--3429",

journal = "Angewandte Chemie International Edition in English",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "12",

}

TY - JOUR

T1 - Broadband inversion PELDOR spectroscopy with partially adiabatic shaped pulses

AU - Spindler, Philipp E.

AU - Glaser, Steffen J.

AU - Skinner, Thomas E.

AU - Prisner, Thomas F.

PY - 2013/3/18

Y1 - 2013/3/18

N2 - Distance and spins: A new broadband, frequency-selective inversion pulse has been devised for pulsed electron-electron double resonance (PELDOR) spectroscopy, a unique method used to determine distance distributions between two or more paramagnetic centers 2-10 nm apart. The PELDOR modulation depth can be increased by substituting the rectangular pump pulse by a shaped pulse.

AB - Distance and spins: A new broadband, frequency-selective inversion pulse has been devised for pulsed electron-electron double resonance (PELDOR) spectroscopy, a unique method used to determine distance distributions between two or more paramagnetic centers 2-10 nm apart. The PELDOR modulation depth can be increased by substituting the rectangular pump pulse by a shaped pulse.

KW - EPR spectroscopy

KW - PELDOR

KW - adiabatic pulses

KW - broadband inversion pulses

KW - transition-metal ions

UR - https://www.scopus.com/pages/publications/84875193617

U2 - 10.1002/anie.201207777

DO - 10.1002/anie.201207777

M3 - Article

C2 - 23424088

AN - SCOPUS:84875193617

SN - 1433-7851

VL - 52

SP - 3425

EP - 3429

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 12

ER -

Broadband inversion PELDOR spectroscopy with partially adiabatic shaped pulses

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this