Bis(1,3,5‐trimethylbenzene)indium(I) Tetrabromoindate(III), the First Arene Complex of Indium

Jan Ebenhöch; Gerhard Müller; Jürgen Riede; Hubert Schmidbaur

doi:10.1002/anie.198403861

Bis(1,3,5‐trimethylbenzene)indium(I) Tetrabromoindate(III), the First Arene Complex of Indium

Jan Ebenhöch, Gerhard Müller, Jürgen Riede, Hubert Schmidbaur

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Arene complexes of main group elements are still a rarity. In[InBr₄] reacts directly with 1,3,5‐trimethylbenzene to give the crystalline 1 : 2‐compound 1. The central atom is additionally bonded to three coplanar bromine atoms; an overall one‐dimensional coordination polymer is formed. (Figure Presented.)

Original language	English
Pages (from-to)	386-388
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	23
Issue number	5
DOIs	https://doi.org/10.1002/anie.198403861
State	Published - May 1984
Externally published	Yes

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title = "Bis(1,3,5‐trimethylbenzene)indium(I) Tetrabromoindate(III), the First Arene Complex of Indium",

abstract = "Arene complexes of main group elements are still a rarity. In[InBr4] reacts directly with 1,3,5‐trimethylbenzene to give the crystalline 1 : 2‐compound 1. The central atom is additionally bonded to three coplanar bromine atoms; an overall one‐dimensional coordination polymer is formed. (Figure Presented.)",

author = "Jan Ebenh{\"o}ch and Gerhard M{\"u}ller and J{\"u}rgen Riede and Hubert Schmidbaur",

year = "1984",

month = may,

doi = "10.1002/anie.198403861",

language = "English",

volume = "23",

pages = "386--388",

journal = "Angewandte Chemie International Edition in English",

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T1 - Bis(1,3,5‐trimethylbenzene)indium(I) Tetrabromoindate(III), the First Arene Complex of Indium

AU - Ebenhöch, Jan

AU - Müller, Gerhard

AU - Riede, Jürgen

AU - Schmidbaur, Hubert

PY - 1984/5

Y1 - 1984/5

N2 - Arene complexes of main group elements are still a rarity. In[InBr4] reacts directly with 1,3,5‐trimethylbenzene to give the crystalline 1 : 2‐compound 1. The central atom is additionally bonded to three coplanar bromine atoms; an overall one‐dimensional coordination polymer is formed. (Figure Presented.)

AB - Arene complexes of main group elements are still a rarity. In[InBr4] reacts directly with 1,3,5‐trimethylbenzene to give the crystalline 1 : 2‐compound 1. The central atom is additionally bonded to three coplanar bromine atoms; an overall one‐dimensional coordination polymer is formed. (Figure Presented.)

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U2 - 10.1002/anie.198403861

DO - 10.1002/anie.198403861

M3 - Article

AN - SCOPUS:84985579396

SN - 0570-0833

VL - 23

SP - 386

EP - 388

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 5

ER -

Bis(1,3,5‐trimethylbenzene)indium(I) Tetrabromoindate(III), the First Arene Complex of Indium

Abstract

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