Bis-Phosphinimino-Silanes as bidentate ligands to metal alkyls

Hubert Schmidbaur; Werner Wolfsberger

doi:10.1080/00945717108057260

Bis-Phosphinimino-Silanes as bidentate ligands to metal alkyls

Hubert Schmidbaur, Werner Wolfsberger

University of Würzburg

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Bis-trimethylphosphinimino-dimethylsilane has been shown to react with dimethyl and diethyl zinc as well as with dimethyl cadmium (not with dimethyl mercury) forming crystalline 1:1 complexes, in which the phosphinimin is acting as a 1,3-bidentate ligand to the tetracoordinate metal atoms.

Original language	English
Pages (from-to)	111-116
Number of pages	6
Journal	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume	1
Issue number	2
DOIs	https://doi.org/10.1080/00945717108057260
State	Published - 1 Jan 1971
Externally published	Yes

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10.1080/00945717108057260

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title = "Bis-Phosphinimino-Silanes as bidentate ligands to metal alkyls",

abstract = "Bis-trimethylphosphinimino-dimethylsilane has been shown to react with dimethyl and diethyl zinc as well as with dimethyl cadmium (not with dimethyl mercury) forming crystalline 1:1 complexes, in which the phosphinimin is acting as a 1,3-bidentate ligand to the tetracoordinate metal atoms.",

author = "Hubert Schmidbaur and Werner Wolfsberger",

year = "1971",

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AU - Wolfsberger, Werner

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N2 - Bis-trimethylphosphinimino-dimethylsilane has been shown to react with dimethyl and diethyl zinc as well as with dimethyl cadmium (not with dimethyl mercury) forming crystalline 1:1 complexes, in which the phosphinimin is acting as a 1,3-bidentate ligand to the tetracoordinate metal atoms.

AB - Bis-trimethylphosphinimino-dimethylsilane has been shown to react with dimethyl and diethyl zinc as well as with dimethyl cadmium (not with dimethyl mercury) forming crystalline 1:1 complexes, in which the phosphinimin is acting as a 1,3-bidentate ligand to the tetracoordinate metal atoms.

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M3 - Article

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JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

IS - 2

ER -

Bis-Phosphinimino-Silanes as bidentate ligands to metal alkyls

Abstract

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