Bis-Phosphinimino-Silanes as bidentate ligands to metal alkyls

Hubert Schmidbaur, Werner Wolfsberger

Research output: Contribution to journalArticlepeer-review

7 Scopus citations


Bis-trimethylphosphinimino-dimethylsilane has been shown to react with dimethyl and diethyl zinc as well as with dimethyl cadmium (not with dimethyl mercury) forming crystalline 1:1 complexes, in which the phosphinimin is acting as a 1,3-bidentate ligand to the tetracoordinate metal atoms.

Original languageEnglish
Pages (from-to)111-116
Number of pages6
JournalSynthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Issue number2
StatePublished - 1 Jan 1971
Externally publishedYes


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