BINEPINES: Chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis

Serafino Gladiali, Elisabetta Alberico, Kathrin Junge, Matthias Beller

Research output: Contribution to journalArticlepeer-review

60 Scopus citations

Abstract

The atropisomeric structure of 4,5-dihydro-3H-dinaphtho[2,1-c;1′,2′e]phosphepine is the common axially chiral scaffold of a library of monophosphine ligands nicknamed BINEPINES that have shown a quite remarkable stereoselection efficiency in a broad variety of enantioselective reactions involving the formation of new C–H or C–C or C–X bonds. In this critical review the properties and scope of this type of chiral ligands are illustrated (70 references).

Original languageEnglish
Pages (from-to)3744-3763
Number of pages20
JournalChemical Society Reviews
Volume40
Issue number7
DOIs
StatePublished - 20 Jun 2011
Externally publishedYes

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