Beiträge zur organosiliciumchemie der sulfoximine. II. Umsilylierungsexperimente

Werner Wolfsberger; Hubert Schmidbaur

doi:10.1016/S0022-328X(00)88012-2

Beiträge zur organosiliciumchemie der sulfoximine. II. Umsilylierungsexperimente

Werner Wolfsberger
, Hubert Schmidbaur

University of Würzburg

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A series of new silylated sulfoximines has been prepared by transsilylation experiments. In the course of these reactions the trimethylsilyl groups of (CH₃)₂S(O)NSi(CH₃)₃ were replaced by functional halosilyl ligands -SiR₂X, -SiRX₂, or -SiX₃, respectively. Upon heating, the products undergo a redistribution reaction which leads to bis(sulfoximino)silane species [(CH₃)₂S(O)N]₂SiRX with X = R or Hal. All compounds were characterized by elemental analysis, molecular weights, IR and NMR spectra. In two cases the experiments have been extended to include the germanium analogs.

Original language	German
Pages (from-to)	317-323
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	28
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)88012-2
State	Published - 1 May 1971
Externally published	Yes

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abstract = "A series of new silylated sulfoximines has been prepared by transsilylation experiments. In the course of these reactions the trimethylsilyl groups of (CH3)2S(O)NSi(CH3)3 were replaced by functional halosilyl ligands -SiR2X, -SiRX2, or -SiX3, respectively. Upon heating, the products undergo a redistribution reaction which leads to bis(sulfoximino)silane species [(CH3)2S(O)N]2SiRX with X = R or Hal. All compounds were characterized by elemental analysis, molecular weights, IR and NMR spectra. In two cases the experiments have been extended to include the germanium analogs.",

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doi = "10.1016/S0022-328X(00)88012-2",

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AU - Schmidbaur, Hubert

PY - 1971/5/1

Y1 - 1971/5/1

N2 - A series of new silylated sulfoximines has been prepared by transsilylation experiments. In the course of these reactions the trimethylsilyl groups of (CH3)2S(O)NSi(CH3)3 were replaced by functional halosilyl ligands -SiR2X, -SiRX2, or -SiX3, respectively. Upon heating, the products undergo a redistribution reaction which leads to bis(sulfoximino)silane species [(CH3)2S(O)N]2SiRX with X = R or Hal. All compounds were characterized by elemental analysis, molecular weights, IR and NMR spectra. In two cases the experiments have been extended to include the germanium analogs.

AB - A series of new silylated sulfoximines has been prepared by transsilylation experiments. In the course of these reactions the trimethylsilyl groups of (CH3)2S(O)NSi(CH3)3 were replaced by functional halosilyl ligands -SiR2X, -SiRX2, or -SiX3, respectively. Upon heating, the products undergo a redistribution reaction which leads to bis(sulfoximino)silane species [(CH3)2S(O)N]2SiRX with X = R or Hal. All compounds were characterized by elemental analysis, molecular weights, IR and NMR spectra. In two cases the experiments have been extended to include the germanium analogs.

UR - https://www.scopus.com/pages/publications/49649150421

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DO - 10.1016/S0022-328X(00)88012-2

M3 - Artikel

AN - SCOPUS:49649150421

SN - 0022-328X

VL - 28

SP - 317

EP - 323

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Beiträge zur organosiliciumchemie der sulfoximine. II. Umsilylierungsexperimente

Abstract

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