Beiträge zur organosiliciumchemie der sulfoximine. II. Umsilylierungsexperimente

Werner Wolfsberger, Hubert Schmidbaur

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Abstract

A series of new silylated sulfoximines has been prepared by transsilylation experiments. In the course of these reactions the trimethylsilyl groups of (CH3)2S(O)NSi(CH3)3 were replaced by functional halosilyl ligands -SiR2X, -SiRX2, or -SiX3, respectively. Upon heating, the products undergo a redistribution reaction which leads to bis(sulfoximino)silane species [(CH3)2S(O)N]2SiRX with X = R or Hal. All compounds were characterized by elemental analysis, molecular weights, IR and NMR spectra. In two cases the experiments have been extended to include the germanium analogs.

Original languageGerman
Pages (from-to)317-323
Number of pages7
JournalJournal of Organometallic Chemistry
Volume28
Issue number3
DOIs
StatePublished - 1 May 1971
Externally publishedYes

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