Baseninduzierte CC-Kupplungsreaktionen an η2-Thiocarbenliganden - Synthese von η3-Thioketencomplexen des Wolframs

Norbert Ullrich; Hans Keller; Claudia Stegmair; Fritz R. Kreissl

doi:10.1016/0022-328X(89)85375-6

Baseninduzierte CC-Kupplungsreaktionen an η²-Thiocarbenliganden - Synthese von η³-Thioketencomplexen des Wolframs

Norbert Ullrich, Hans Keller, Claudia Stegmair, Fritz R. Kreissl

Life Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Dicarbonyl(η⁵-cyclopentadienyl)[η²-aryl(methylthio)carbene]tungsten tetrafluoroborate reacts with trimethylphosphine to give first an intermediate cationic η³-thioketene complex which adds trimethylphosphine to yield a cationic tungsta-oxa-thia-cyclopentene ring system.

Original language	English
Pages (from-to)	C19-C22
Journal	Journal of Organometallic Chemistry
Volume	378
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(89)85375-6
State	Published - 12 Dec 1989

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title = "Baseninduzierte CC-Kupplungsreaktionen an η2-Thiocarbenliganden - Synthese von η3-Thioketencomplexen des Wolframs",

abstract = "Dicarbonyl(η5-cyclopentadienyl)[η2-aryl(methylthio)carbene]tungsten tetrafluoroborate reacts with trimethylphosphine to give first an intermediate cationic η3-thioketene complex which adds trimethylphosphine to yield a cationic tungsta-oxa-thia-cyclopentene ring system.",

author = "Norbert Ullrich and Hans Keller and Claudia Stegmair and Kreissl, {Fritz R.}",

year = "1989",

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doi = "10.1016/0022-328X(89)85375-6",

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AU - Ullrich, Norbert

AU - Keller, Hans

AU - Stegmair, Claudia

AU - Kreissl, Fritz R.

PY - 1989/12/12

Y1 - 1989/12/12

N2 - Dicarbonyl(η5-cyclopentadienyl)[η2-aryl(methylthio)carbene]tungsten tetrafluoroborate reacts with trimethylphosphine to give first an intermediate cationic η3-thioketene complex which adds trimethylphosphine to yield a cationic tungsta-oxa-thia-cyclopentene ring system.

AB - Dicarbonyl(η5-cyclopentadienyl)[η2-aryl(methylthio)carbene]tungsten tetrafluoroborate reacts with trimethylphosphine to give first an intermediate cationic η3-thioketene complex which adds trimethylphosphine to yield a cationic tungsta-oxa-thia-cyclopentene ring system.

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DO - 10.1016/0022-328X(89)85375-6

M3 - Article

AN - SCOPUS:0042276182

SN - 0022-328X

VL - 378

SP - C19-C22

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Baseninduzierte CC-Kupplungsreaktionen an η²-Thiocarbenliganden - Synthese von η³-Thioketencomplexen des Wolframs

Abstract

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