Base-free hydrogen generation from methanol using a bi-catalytic system

Angèle Monney, Enrico Barsch, Peter Sponholz, Henrik Junge, Ralf Ludwig, Matthias Beller

Research output: Contribution to journalArticlepeer-review

120 Scopus citations

Abstract

A bi-catalytic system, in which Ru-MACHO-BH and Ru(H)2(dppe)2 interact in a synergistic manner, was developed for the base-free dehydrogenation of methanol. A total TON > 4200 was obtained with only trace amounts of CO contamination (<8 ppm) in the produced gas.

Original languageEnglish
Pages (from-to)707-709
Number of pages3
JournalChemical Communications
Volume50
Issue number6
DOIs
StatePublished - 12 Dec 2014
Externally publishedYes

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