Ballistic anomalies in solid rocket motors due to migration effects

Double base and composite propellants are generally used for rocket motors, whereby double base propellants basically consist of nitrocellulose plasticized with an explosive plasticizer, mostly nitroglycerine, and in some cases with an additional inert plasticizer and ballistic additives. Composite propellants consist of an oxidizer like ammonium perchlorate and of aluminum, binder and plasticizer and often contain liquid or solid burning rate catalysts. A common feature of both propellants is that they contain smaller or larger amounts of chemically unbonded liquid species which tend to migrate. If these propellants loose part of the plasticizer by migration into the insulation layer, not only will there be a change in mechanical propellant properties but also the bond between propellant and insulation may degrade. However, depending on the severity of these effects, the change in the ballistic properties of the propellant grain caused by plasticizer migration may be of even more importance. In the past, most emphasis was placed on the behaviour of end-burning configurations. However, more recent theoretical and experimental studies revealed that not only for end-burning grain configurations but also for internal burning configurations there is a common effect which is responsible for ballistic anomalies: migration of liquid species from the propellant into the insulation. By using a plasticizer equilibrated insulation in an internal burning configuration the liquid species migration and thus the previously observed ballistic anomalies are avoided. Using this approach for end-burning configurations provides similar positive results. The various factors affecting plasticizer migration are studied and discussed, and several methods to prevent liquid species migration are described as well as methods to obtain plasticizer resistant insulations.