B-N Chemistry@ZIF-8: Dehydrocoupling of dimethylamine borane at room temperature by size-confinement effects

Suresh Babu Kalidindi; Daniel Esken; Roland A. Fischer

doi:10.1002/chem.201100518

B-N Chemistry@ZIF-8: Dehydrocoupling of dimethylamine borane at room temperature by size-confinement effects

Suresh Babu Kalidindi
, Daniel Esken
, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Confined coupling: A dimethylamine borane adduct undergoes catalytic dehydrocoupling inside a zeolite-imidazole framework (ZIF-8) to yield the cyclic dimer (Me₂N·BH₂)₂ under mild conditions owing to strong caging effects (see graphic).

Original language	English
Pages (from-to)	6594-6597
Number of pages	4
Journal	Chemistry - A European Journal
Volume	17
Issue number	24
DOIs	https://doi.org/10.1002/chem.201100518
State	Published - 6 Jun 2011
Externally published	Yes

Keywords

cage compounds
dimethylamine borane
heterogeneous catalysis
hydrogen storage
metal-organic frameworks

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10.1002/chem.201100518

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@article{3c28d11f3e6940c5b068595f72297fab,

title = "B-N Chemistry@ZIF-8: Dehydrocoupling of dimethylamine borane at room temperature by size-confinement effects",

abstract = "Confined coupling: A dimethylamine borane adduct undergoes catalytic dehydrocoupling inside a zeolite-imidazole framework (ZIF-8) to yield the cyclic dimer (Me2N·BH2)2 under mild conditions owing to strong caging effects (see graphic).",

keywords = "cage compounds, dimethylamine borane, heterogeneous catalysis, hydrogen storage, metal-organic frameworks",

author = "Kalidindi, \{Suresh Babu\} and Daniel Esken and Fischer, \{Roland A.\}",

year = "2011",

month = jun,

day = "6",

doi = "10.1002/chem.201100518",

language = "English",

volume = "17",

pages = "6594--6597",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc.",

number = "24",

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TY - JOUR

T1 - B-N Chemistry@ZIF-8

T2 - Dehydrocoupling of dimethylamine borane at room temperature by size-confinement effects

AU - Kalidindi, Suresh Babu

AU - Esken, Daniel

AU - Fischer, Roland A.

PY - 2011/6/6

Y1 - 2011/6/6

N2 - Confined coupling: A dimethylamine borane adduct undergoes catalytic dehydrocoupling inside a zeolite-imidazole framework (ZIF-8) to yield the cyclic dimer (Me2N·BH2)2 under mild conditions owing to strong caging effects (see graphic).

AB - Confined coupling: A dimethylamine borane adduct undergoes catalytic dehydrocoupling inside a zeolite-imidazole framework (ZIF-8) to yield the cyclic dimer (Me2N·BH2)2 under mild conditions owing to strong caging effects (see graphic).

KW - cage compounds

KW - dimethylamine borane

KW - heterogeneous catalysis

KW - hydrogen storage

KW - metal-organic frameworks

UR - https://www.scopus.com/pages/publications/79957948434

U2 - 10.1002/chem.201100518

DO - 10.1002/chem.201100518

M3 - Article

AN - SCOPUS:79957948434

SN - 0947-6539

VL - 17

SP - 6594

EP - 6597

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 24

ER -

B-N Chemistry@ZIF-8: Dehydrocoupling of dimethylamine borane at room temperature by size-confinement effects

Abstract

Keywords

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