Assembly of the [CAu6]2⊕ Cluster with a Tailor‐made Diphosphane Spanning the Octahedral Edges

Oliver Steigelmann, Peter Bissinger, Hubert Schmidbaur

Research output: Contribution to journalArticlepeer-review

51 Scopus citations

Abstract

Digold complexes bridged via chelate ligands are also suitable for the molecular “gilding” of carbon atoms, as shown by the structure of the CAu6, complex cation 1. Due to the asymmetry of the ligand sphere the cations are chiral. The formation of 1 demonstrates that the aurophilicity concept can also be extended to bidentate ligands. (Figure Presented.)

Original languageEnglish
Pages (from-to)1399-1400
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume29
Issue number12
DOIs
StatePublished - Dec 1990
Externally publishedYes

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