Artificial host molecules for the sensing of anions

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

64 Scopus citations

Abstract

The foundations of supramolecular complexation of anions by abiotic host compounds are evaluated, with the purpose of determining their qualitative and quantitative preference over competing species. Starting from a critical assessment of binding models, the perspective goal in terms of molecular thermodynamics is defined and discussed. General consequences for the strategic design of artificial anion hosts are delineated and their translation into receptor structures is suggested. The usage of the available fundamental interaction types for anion binding is illustrated with the help of prototypical, yet concrete, receptors of proven utility.

Original languageEnglish
Title of host publicationAnion Sensing
EditorsIvan Stibori
Pages1-29
Number of pages29
DOIs
StatePublished - 28 Apr 2005

Publication series

NameTopics in Current Chemistry
Volume255
ISSN (Print)0340-1022

Keywords

  • Anion host
  • Binding models
  • Host-guest chemistry
  • Statistical thermodynamics
  • Supramolecular association

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