Aromaten-Komplexe der p-Block-Elemente: Eine Tetramere η6-Koordinationsverbindung des Hexamethylbenzols mit Sn(AlCl4)Cl und Kristall-Chlorbenzol

Hubert Schmidbaur; Thomas Probst; Brigitte Huber; Gerhard Müller; Carl Krüger

doi:10.1016/0022-328X(89)87166-9

Aromaten-Komplexe der p-Block-Elemente: Eine Tetramere η⁶-Koordinationsverbindung des Hexamethylbenzols mit Sn(AlCl₄)Cl und Kristall-Chlorbenzol

Hubert Schmidbaur, Thomas Probst, Brigitte Huber, Gerhard Müller, Carl Krüger

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

The compound [η⁵-(C₆Me₆)SnCl(AlCl₄)]₄ has been prepared from Sn(AlCl₄)₂ and hexamethylbenzene in chlorobenzene as solvent. Its crystal structure has been determined from single crystal X-ray diffraction. The structure is composed of dimeric units [η⁶-(C₆Me₆)SnCl(AlCl₄)]₂ containing crystallographically nonequivalent monomers. These dimers are cross-linked to form centrosymmetrical tetramers. The C₆Me₆ aromatic rings are η⁶-bonded to the tin atoms, while the crystalchlorobenzene molecules have no metal contacts. Pb(AlBr₄)₂ crystallizes from benzene as a polycoordinate network, in which the Pb¹¹ centers are eight-coordinate to the bromine atoms of four chelating AlBr₄ units. The solvating benzene has no metal contact.

Original language	German
Pages (from-to)	53-60
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	365
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(89)87166-9
State	Published - 11 Apr 1989

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@article{78633210a55644e1acf9da800fea2e57,

title = "Aromaten-Komplexe der p-Block-Elemente: Eine Tetramere η6-Koordinationsverbindung des Hexamethylbenzols mit Sn(AlCl4)Cl und Kristall-Chlorbenzol",

abstract = "The compound [η5-(C6Me6)SnCl(AlCl4)]4 has been prepared from Sn(AlCl4)2 and hexamethylbenzene in chlorobenzene as solvent. Its crystal structure has been determined from single crystal X-ray diffraction. The structure is composed of dimeric units [η6-(C6Me6)SnCl(AlCl4)]2 containing crystallographically nonequivalent monomers. These dimers are cross-linked to form centrosymmetrical tetramers. The C6Me6 aromatic rings are η6-bonded to the tin atoms, while the crystalchlorobenzene molecules have no metal contacts. Pb(AlBr4)2 crystallizes from benzene as a polycoordinate network, in which the Pb11 centers are eight-coordinate to the bromine atoms of four chelating AlBr4 units. The solvating benzene has no metal contact.",

author = "Hubert Schmidbaur and Thomas Probst and Brigitte Huber and Gerhard M{\"u}ller and Carl Kr{\"u}ger",

year = "1989",

month = apr,

day = "11",

doi = "10.1016/0022-328X(89)87166-9",

language = "Deutsch",

volume = "365",

pages = "53--60",

journal = "Journal of Organometallic Chemistry",

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number = "1-2",

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T1 - Aromaten-Komplexe der p-Block-Elemente

T2 - Eine Tetramere η6-Koordinationsverbindung des Hexamethylbenzols mit Sn(AlCl4)Cl und Kristall-Chlorbenzol

AU - Schmidbaur, Hubert

AU - Probst, Thomas

AU - Huber, Brigitte

AU - Müller, Gerhard

AU - Krüger, Carl

PY - 1989/4/11

Y1 - 1989/4/11

N2 - The compound [η5-(C6Me6)SnCl(AlCl4)]4 has been prepared from Sn(AlCl4)2 and hexamethylbenzene in chlorobenzene as solvent. Its crystal structure has been determined from single crystal X-ray diffraction. The structure is composed of dimeric units [η6-(C6Me6)SnCl(AlCl4)]2 containing crystallographically nonequivalent monomers. These dimers are cross-linked to form centrosymmetrical tetramers. The C6Me6 aromatic rings are η6-bonded to the tin atoms, while the crystalchlorobenzene molecules have no metal contacts. Pb(AlBr4)2 crystallizes from benzene as a polycoordinate network, in which the Pb11 centers are eight-coordinate to the bromine atoms of four chelating AlBr4 units. The solvating benzene has no metal contact.

AB - The compound [η5-(C6Me6)SnCl(AlCl4)]4 has been prepared from Sn(AlCl4)2 and hexamethylbenzene in chlorobenzene as solvent. Its crystal structure has been determined from single crystal X-ray diffraction. The structure is composed of dimeric units [η6-(C6Me6)SnCl(AlCl4)]2 containing crystallographically nonequivalent monomers. These dimers are cross-linked to form centrosymmetrical tetramers. The C6Me6 aromatic rings are η6-bonded to the tin atoms, while the crystalchlorobenzene molecules have no metal contacts. Pb(AlBr4)2 crystallizes from benzene as a polycoordinate network, in which the Pb11 centers are eight-coordinate to the bromine atoms of four chelating AlBr4 units. The solvating benzene has no metal contact.

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U2 - 10.1016/0022-328X(89)87166-9

DO - 10.1016/0022-328X(89)87166-9

M3 - Artikel

AN - SCOPUS:0011566323

SN - 0022-328X

VL - 365

SP - 53

EP - 60

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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ER -

Aromaten-Komplexe der p-Block-Elemente: Eine Tetramere η6-Koordinationsverbindung des Hexamethylbenzols mit Sn(AlCl4)Cl und Kristall-Chlorbenzol

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Aromaten-Komplexe der p-Block-Elemente: Eine Tetramere η⁶-Koordinationsverbindung des Hexamethylbenzols mit Sn(AlCl₄)Cl und Kristall-Chlorbenzol