Anomalous Nucleophilic Substitution in (Chloromethyl)silane: 1,2‐Hydride Shift

Hubert Schmidbaur, Beate Zimmer‐Gasser

Research output: Contribution to journalArticlepeer-review

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H3SiCH2Cl1 and its analog H3CCH2Cl differ in the polarity of the CCl bond. The first reactions of 1 have now been found which proceed differently from those of the “true” alkyl compound. (RCH3 or C2H5; repeated silylation finally affords R3PC(SiH2CH3)2). (Figure Presented.)

Original languageEnglish
Pages (from-to)639-640
Number of pages2
JournalAngewandte Chemie International Edition in English
Issue number9
StatePublished - Sep 1977
Externally publishedYes


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