Analysis and modeling of calendar aging of a commercial LiFePO₄/graphite cell

This paper presents a comprehensive calendar aging study on a lithium-ion battery with a test duration of 29 months. This aging study was realized with a widely used commercial LiFePO₄/graphite cell from Sony/Murata, which promises both long calendar and cycle lifetime, which is especially required for stationary battery applications. The development of the cells’ capacity, as well as the resistances, are shown in a static calendar aging study for 17 test points, each with 3 cells, having constant storage conditions of temperature and state of charge. Based on the measurement data, a semi-empirical aging model is presented for the capacity loss and resistance increase, consisting of only 5 parameters which are valid for all storage conditions. An additional dynamic calendar aging study is performed with 9 months test duration for model validation, consisting of 15 test points with varying conditions of temperature and state of charge. The absolute model errors against the validation data points remain below 2.2% for the capacity loss and below 6.9% for the resistance increase for all dynamic validation tests. In conclusion, this calendar aging model allows the prognosis of the calendar lifetime of LiFePO₄/graphite batteries in different applications with varying storage conditions over time.