An isolable bis-silylene oxide ("Disilylenoxane") and its metal coordination

Wenyuan Wang; Shigeyoshi Inoue; Shenglai Yao; Matthias Driess

doi:10.1021/ja106458p

An isolable bis-silylene oxide ("Disilylenoxane") and its metal coordination

Wenyuan Wang
, Shigeyoshi Inoue
, Shenglai Yao
, Matthias Driess

Technische Universität Berlin

Research output: Contribution to journal › Article › peer-review

108 Scopus citations

Abstract

The first isolable oxygen-bridged bis-silylene 1 has been synthesized by facile dehydrochloration of the corresponding disiloxane [LSiH(Cl)-O-SiH(Cl)L] precursor [L = PhC(NtBu)₂] with LiN(SiMe₃)₂. Compound 1 contains three-coordinate, pyramidal Si(II) atoms in a bent disiloxane-like moiety and reacts readily with [Ni(COD)₂] to afford the unique bis-silylene oxide nickel complex 3.

Original language	English
Pages (from-to)	15890-15892
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	132
Issue number	45
DOIs	https://doi.org/10.1021/ja106458p
State	Published - 17 Nov 2010
Externally published	Yes

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abstract = "The first isolable oxygen-bridged bis-silylene 1 has been synthesized by facile dehydrochloration of the corresponding disiloxane [LSiH(Cl)-O-SiH(Cl)L] precursor [L = PhC(NtBu)2] with LiN(SiMe3)2. Compound 1 contains three-coordinate, pyramidal Si(II) atoms in a bent disiloxane-like moiety and reacts readily with [Ni(COD)2] to afford the unique bis-silylene oxide nickel complex 3.",

author = "Wenyuan Wang and Shigeyoshi Inoue and Shenglai Yao and Matthias Driess",

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T1 - An isolable bis-silylene oxide ("Disilylenoxane") and its metal coordination

AU - Wang, Wenyuan

AU - Inoue, Shigeyoshi

AU - Yao, Shenglai

AU - Driess, Matthias

PY - 2010/11/17

Y1 - 2010/11/17

N2 - The first isolable oxygen-bridged bis-silylene 1 has been synthesized by facile dehydrochloration of the corresponding disiloxane [LSiH(Cl)-O-SiH(Cl)L] precursor [L = PhC(NtBu)2] with LiN(SiMe3)2. Compound 1 contains three-coordinate, pyramidal Si(II) atoms in a bent disiloxane-like moiety and reacts readily with [Ni(COD)2] to afford the unique bis-silylene oxide nickel complex 3.

AB - The first isolable oxygen-bridged bis-silylene 1 has been synthesized by facile dehydrochloration of the corresponding disiloxane [LSiH(Cl)-O-SiH(Cl)L] precursor [L = PhC(NtBu)2] with LiN(SiMe3)2. Compound 1 contains three-coordinate, pyramidal Si(II) atoms in a bent disiloxane-like moiety and reacts readily with [Ni(COD)2] to afford the unique bis-silylene oxide nickel complex 3.

UR - https://www.scopus.com/pages/publications/78449264484

U2 - 10.1021/ja106458p

DO - 10.1021/ja106458p

M3 - Article

AN - SCOPUS:78449264484

SN - 0002-7863

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EP - 15892

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 45

ER -

An isolable bis-silylene oxide ("Disilylenoxane") and its metal coordination

Abstract

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