An aluminium-oxide-isopropoxide cluster with peripheral ammonia ligands

Upendra M. Tripathi, Annette Schier, Hubert Schmidbaur

Research output: Contribution to journalArticlepeer-review

4 Scopus citations

Abstract

The reaction of toluene solutions of aluminium isopropoxide with ammonia gas, without exclusion of moisture, affords high yields of a decanuclear aluminium-oxide-isopropoxide-ammonia cluster of the composition [Al10O6(OiPr)18(NH3)8]. The compact centrosymmetric cluster units feature tetra-, penta-and hexa-coordinate aluminium atoms, tri-and tetra-coordinate interstitial oxygen atoms, and bridging and terminal isopropoxide groups. The ammonia molecules occupy peripheral positions at two types of aluminium atoms.

Original languageEnglish
Pages (from-to)434-437
Number of pages4
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume53
Issue number4
DOIs
StatePublished - Apr 1998
Externally publishedYes

Keywords

  • Aluminium Isopropoxide
  • Aluminium Oxide Isopropoxide
  • Ammonia Complex
  • Cluster

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