An acyclic imino-substituted silylene: Synthesis, isolation, and its facile conversion into a zwitterionic silaimine

Shigeyoshi Inoue; Kinga Leszczyńska

doi:10.1002/anie.201203257

An acyclic imino-substituted silylene: Synthesis, isolation, and its facile conversion into a zwitterionic silaimine

Shigeyoshi Inoue, Kinga Leszczyńska

Technische Universität Berlin

Research output: Contribution to journal › Article › peer-review

86 Scopus citations

Abstract

A new type of Si(II): A novel silylene stabilized by a Cp* and an imidazolin-2-iminato ligand has been prepared using two different methods (see scheme). The X-ray crystallographic structure shows that the silicon(II) center is coordinated to an ?2-Cp* ligand and the nitrogen atom of an imidazolin-2-iminato ligand. This silylene easily reacts with B(C6F5)3 to give a stable borane adduct having a zwitterionic resonance structure.

Original language	English
Pages (from-to)	8589-8593
Number of pages	5
Journal	Angewandte Chemie International Edition in English
Volume	51
Issue number	34
DOIs	https://doi.org/10.1002/anie.201203257
State	Published - 20 Aug 2012
Externally published	Yes

Keywords

X-ray structures
carbenes
density functional calculations
silicon
silylenes

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KW - X-ray structures

KW - carbenes

KW - density functional calculations

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KW - silylenes

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An acyclic imino-substituted silylene: Synthesis, isolation, and its facile conversion into a zwitterionic silaimine

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Keywords

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