Alkyne Coordination to Organorhenium Oxides with Rhenium in High Oxidation States

Josef K. Felixberger; Josef G. Kuchler; Eberhardt Herdtweck; Rocco A. Paciello; Wolfgang A. Herrmann

doi:10.1002/anie.198809461

Alkyne Coordination to Organorhenium Oxides with Rhenium in High Oxidation States

Josef K. Felixberger
, Josef G. Kuchler
, Eberhardt Herdtweck
, Rocco A. Paciello
, Wolfgang A. Herrmann

Technical University of Munich

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

Methylrhenium(VII) oxide 1 is an excellent starting substance for the synthesis of rhenium complexes with π‐alkyne ligands. As depicted below, the oxygen‐abstracting effect of polymer‐bound triphenylphosphane ℗ can be exploited for the production of the new complexes. 2. According to theoretical studies the existence of such Re^V compounds was highly improbable. Reduction of 2, R  R′  Me, led to the first Re^IV‐alkyne complex 3. (Figure Presented.)

Original language	English
Pages (from-to)	946-948
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	27
Issue number	7
DOIs	https://doi.org/10.1002/anie.198809461
State	Published - Jul 1988

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title = "Alkyne Coordination to Organorhenium Oxides with Rhenium in High Oxidation States",

abstract = "Methylrhenium(VII) oxide 1 is an excellent starting substance for the synthesis of rhenium complexes with π‐alkyne ligands. As depicted below, the oxygen‐abstracting effect of polymer‐bound triphenylphosphane {\textcircledP} can be exploited for the production of the new complexes. 2. According to theoretical studies the existence of such ReV compounds was highly improbable. Reduction of 2, R  R′  Me, led to the first ReIV‐alkyne complex 3. (Figure Presented.)",

author = "Felixberger, \{Josef K.\} and Kuchler, \{Josef G.\} and Eberhardt Herdtweck and Paciello, \{Rocco A.\} and Herrmann, \{Wolfgang A.\}",

year = "1988",

month = jul,

doi = "10.1002/anie.198809461",

language = "English",

volume = "27",

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journal = "Angewandte Chemie International Edition in English",

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T1 - Alkyne Coordination to Organorhenium Oxides with Rhenium in High Oxidation States

AU - Felixberger, Josef K.

AU - Kuchler, Josef G.

AU - Herdtweck, Eberhardt

AU - Paciello, Rocco A.

AU - Herrmann, Wolfgang A.

PY - 1988/7

Y1 - 1988/7

N2 - Methylrhenium(VII) oxide 1 is an excellent starting substance for the synthesis of rhenium complexes with π‐alkyne ligands. As depicted below, the oxygen‐abstracting effect of polymer‐bound triphenylphosphane ℗ can be exploited for the production of the new complexes. 2. According to theoretical studies the existence of such ReV compounds was highly improbable. Reduction of 2, R  R′  Me, led to the first ReIV‐alkyne complex 3. (Figure Presented.)

AB - Methylrhenium(VII) oxide 1 is an excellent starting substance for the synthesis of rhenium complexes with π‐alkyne ligands. As depicted below, the oxygen‐abstracting effect of polymer‐bound triphenylphosphane ℗ can be exploited for the production of the new complexes. 2. According to theoretical studies the existence of such ReV compounds was highly improbable. Reduction of 2, R  R′  Me, led to the first ReIV‐alkyne complex 3. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84990149211

U2 - 10.1002/anie.198809461

DO - 10.1002/anie.198809461

M3 - Article

AN - SCOPUS:84990149211

SN - 0570-0833

VL - 27

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JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 7

ER -

Alkyne Coordination to Organorhenium Oxides with Rhenium in High Oxidation States

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