TY - JOUR
T1 - Alkyne Coordination to Organorhenium Oxides with Rhenium in High Oxidation States
AU - Felixberger, Josef K.
AU - Kuchler, Josef G.
AU - Herdtweck, Eberhardt
AU - Paciello, Rocco A.
AU - Herrmann, Wolfgang A.
PY - 1988/7
Y1 - 1988/7
N2 - Methylrhenium(VII) oxide 1 is an excellent starting substance for the synthesis of rhenium complexes with π‐alkyne ligands. As depicted below, the oxygen‐abstracting effect of polymer‐bound triphenylphosphane ℗ can be exploited for the production of the new complexes. 2. According to theoretical studies the existence of such ReV compounds was highly improbable. Reduction of 2, R R′ Me, led to the first ReIV‐alkyne complex 3. (Figure Presented.)
AB - Methylrhenium(VII) oxide 1 is an excellent starting substance for the synthesis of rhenium complexes with π‐alkyne ligands. As depicted below, the oxygen‐abstracting effect of polymer‐bound triphenylphosphane ℗ can be exploited for the production of the new complexes. 2. According to theoretical studies the existence of such ReV compounds was highly improbable. Reduction of 2, R R′ Me, led to the first ReIV‐alkyne complex 3. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=84990149211&partnerID=8YFLogxK
U2 - 10.1002/anie.198809461
DO - 10.1002/anie.198809461
M3 - Article
AN - SCOPUS:84990149211
SN - 0570-0833
VL - 27
SP - 946
EP - 948
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 7
ER -