TY - JOUR
T1 - Alkyltechnetium Oxides
T2 - First Examples and Reactions
AU - Herrmann, Wolfgang A.
AU - Alberto, Roger
AU - Kiprof, Paul
AU - Baumgärtner, Franz
PY - 1990/2
Y1 - 1990/2
N2 - A “diagonal relationship” between technetium(VII) and osmium(VIII) can be proposed based on the properties of the newly synthesized title compounds. Like the valence‐isoelectronic OsO4, MeTcO3 adds olefins to form metallacycles (→cis‐diols), whereas the formally analogous MeReO3 epoxidates olefins in the presence of H2O2. This difference is presumably due to the oxidizing strength of TcVII being much greater than that of ReVII.
AB - A “diagonal relationship” between technetium(VII) and osmium(VIII) can be proposed based on the properties of the newly synthesized title compounds. Like the valence‐isoelectronic OsO4, MeTcO3 adds olefins to form metallacycles (→cis‐diols), whereas the formally analogous MeReO3 epoxidates olefins in the presence of H2O2. This difference is presumably due to the oxidizing strength of TcVII being much greater than that of ReVII.
UR - http://www.scopus.com/inward/record.url?scp=0025366249&partnerID=8YFLogxK
U2 - 10.1002/anie.199001891
DO - 10.1002/anie.199001891
M3 - Article
AN - SCOPUS:0025366249
SN - 0570-0833
VL - 29
SP - 189
EP - 191
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 2
ER -