Alkali metal oxides: Occupied, unoccupied and excited states

E. Bertel; N. Memmel; W. Jacob; V. Dose; F. P. Netzer; G. Rosina; G. Rangelov; G. Astl; N. Rösch; P. Knappe; B. I. Dunlap; H. Saalfeld

doi:10.1007/BF00619703

Alkali metal oxides: Occupied, unoccupied and excited states

E. Bertel, N. Memmel, W. Jacob, V. Dose, F. P. Netzer, G. Rosina, G. Rangelov, G. Astl, N. Rösch, P. Knappe, B. I. Dunlap, H. Saalfeld

Associate Professorship of Theoretical Chemistry (2008 — 2024)

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7 Scopus citations

Abstract

The occupied and unoccupied electronic states of NaO₂ and KO₂ have been investigated by UV photoemission spectroscopy and inverse photoemission spectroscopy, respectively. In addition single electron excitations from occupied into empty levels have been probed by x-ray absorption and electron energy loss spectroscopy. The experimental data are augmented by LCGTO-Xα model cluster calculations. A detailed assignment of initial and final states is given. The excitation cross sections and an inversion of the ligand field induced 3d level splitting in NaO₂ are discussed.

Original language	English
Pages (from-to)	87-89
Number of pages	3
Journal	Applied Physics A Solids and Surfaces
Volume	47
Issue number	1
DOIs	https://doi.org/10.1007/BF00619703
State	Published - Sep 1988

Keywords

71.70Ch
73.60Hy
78.70Dm
79.60Eq

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10.1007/BF00619703

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title = "Alkali metal oxides: Occupied, unoccupied and excited states",

abstract = "The occupied and unoccupied electronic states of NaO2 and KO2 have been investigated by UV photoemission spectroscopy and inverse photoemission spectroscopy, respectively. In addition single electron excitations from occupied into empty levels have been probed by x-ray absorption and electron energy loss spectroscopy. The experimental data are augmented by LCGTO-Xα model cluster calculations. A detailed assignment of initial and final states is given. The excitation cross sections and an inversion of the ligand field induced 3d level splitting in NaO2 are discussed.",

keywords = "71.70Ch, 73.60Hy, 78.70Dm, 79.60Eq",

author = "E. Bertel and N. Memmel and W. Jacob and V. Dose and Netzer, {F. P.} and G. Rosina and G. Rangelov and G. Astl and N. R{\"o}sch and P. Knappe and Dunlap, {B. I.} and H. Saalfeld",

year = "1988",

month = sep,

doi = "10.1007/BF00619703",

language = "English",

volume = "47",

pages = "87--89",

journal = "Applied Physics A Solids and Surfaces",

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publisher = "Springer Verlag",

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TY - JOUR

T1 - Alkali metal oxides

T2 - Occupied, unoccupied and excited states

AU - Bertel, E.

AU - Memmel, N.

AU - Jacob, W.

AU - Dose, V.

AU - Netzer, F. P.

AU - Rosina, G.

AU - Rangelov, G.

AU - Astl, G.

AU - Rösch, N.

AU - Knappe, P.

AU - Dunlap, B. I.

AU - Saalfeld, H.

PY - 1988/9

Y1 - 1988/9

N2 - The occupied and unoccupied electronic states of NaO2 and KO2 have been investigated by UV photoemission spectroscopy and inverse photoemission spectroscopy, respectively. In addition single electron excitations from occupied into empty levels have been probed by x-ray absorption and electron energy loss spectroscopy. The experimental data are augmented by LCGTO-Xα model cluster calculations. A detailed assignment of initial and final states is given. The excitation cross sections and an inversion of the ligand field induced 3d level splitting in NaO2 are discussed.

AB - The occupied and unoccupied electronic states of NaO2 and KO2 have been investigated by UV photoemission spectroscopy and inverse photoemission spectroscopy, respectively. In addition single electron excitations from occupied into empty levels have been probed by x-ray absorption and electron energy loss spectroscopy. The experimental data are augmented by LCGTO-Xα model cluster calculations. A detailed assignment of initial and final states is given. The excitation cross sections and an inversion of the ligand field induced 3d level splitting in NaO2 are discussed.

KW - 71.70Ch

KW - 73.60Hy

KW - 78.70Dm

KW - 79.60Eq

UR - http://www.scopus.com/inward/record.url?scp=0024084893&partnerID=8YFLogxK

U2 - 10.1007/BF00619703

DO - 10.1007/BF00619703

M3 - Article

AN - SCOPUS:0024084893

SN - 0721-7250

VL - 47

SP - 87

EP - 89

JO - Applied Physics A Solids and Surfaces

JF - Applied Physics A Solids and Surfaces

IS - 1

ER -

Alkali metal oxides: Occupied, unoccupied and excited states

Abstract

Keywords

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